A. Boumechhour, S. Benadji, T. Mazari, L. Dermeche, C. Rabia
{"title":"H3-2xMnxPMo12O40 和 (NH4)3-2xMnxPMo12O40 杂多化合物的结构和组成对其在过氧化氢氧化环己酮过程中催化特性的影响","authors":"A. Boumechhour, S. Benadji, T. Mazari, L. Dermeche, C. Rabia","doi":"10.1007/s11237-022-09745-2","DOIUrl":null,"url":null,"abstract":"<div><div><p>Catalytic properties of two series of Keggin-type heteropolycompounds, H<sub>3–2<i>x</i></sub>Mn<sub><i>x</i></sub>PMo<sub>12</sub>O<sub>40</sub> and (NH<sub>4</sub>)<sub>3–2<i>x</i></sub>Mn<sub><i>x</i></sub>PMo<sub>12</sub>O<sub>40</sub> (x = 0.25-1.5), have been studied in the process of oxidation of cyclohexanone and/or cyclohexanol to adipic acid, using 30% hydrogen peroxide, in the absence of organic solvent. The main products and by-products have been identified by means of GC-MS analysis. The highest yields of adipic acid are found in the case of H<sub>1.5</sub>Mn<sub>0.75</sub>PMo<sub>12</sub>O<sub>40</sub> and (NH<sub>4</sub>)<sub>2</sub>Mn<sub>0.5</sub>PMo<sub>12</sub>O<sub>40</sub> compounds.</p></div></div>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":"58 4","pages":"276 - 289"},"PeriodicalIF":0.7000,"publicationDate":"2022-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of the Structure and Composition of H3–2xMnxPMo12O40 AND (NH4)3–2xMnxPMo12O40 Heteropolycompounds on their Catalytic Properties in the Process of Cyclohexanone Oxidation with Hydrogen Peroxide\",\"authors\":\"A. Boumechhour, S. Benadji, T. Mazari, L. Dermeche, C. Rabia\",\"doi\":\"10.1007/s11237-022-09745-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div><p>Catalytic properties of two series of Keggin-type heteropolycompounds, H<sub>3–2<i>x</i></sub>Mn<sub><i>x</i></sub>PMo<sub>12</sub>O<sub>40</sub> and (NH<sub>4</sub>)<sub>3–2<i>x</i></sub>Mn<sub><i>x</i></sub>PMo<sub>12</sub>O<sub>40</sub> (x = 0.25-1.5), have been studied in the process of oxidation of cyclohexanone and/or cyclohexanol to adipic acid, using 30% hydrogen peroxide, in the absence of organic solvent. The main products and by-products have been identified by means of GC-MS analysis. The highest yields of adipic acid are found in the case of H<sub>1.5</sub>Mn<sub>0.75</sub>PMo<sub>12</sub>O<sub>40</sub> and (NH<sub>4</sub>)<sub>2</sub>Mn<sub>0.5</sub>PMo<sub>12</sub>O<sub>40</sub> compounds.</p></div></div>\",\"PeriodicalId\":796,\"journal\":{\"name\":\"Theoretical and Experimental Chemistry\",\"volume\":\"58 4\",\"pages\":\"276 - 289\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2022-12-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Theoretical and Experimental Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11237-022-09745-2\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical and Experimental Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11237-022-09745-2","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Influence of the Structure and Composition of H3–2xMnxPMo12O40 AND (NH4)3–2xMnxPMo12O40 Heteropolycompounds on their Catalytic Properties in the Process of Cyclohexanone Oxidation with Hydrogen Peroxide
Catalytic properties of two series of Keggin-type heteropolycompounds, H3–2xMnxPMo12O40 and (NH4)3–2xMnxPMo12O40 (x = 0.25-1.5), have been studied in the process of oxidation of cyclohexanone and/or cyclohexanol to adipic acid, using 30% hydrogen peroxide, in the absence of organic solvent. The main products and by-products have been identified by means of GC-MS analysis. The highest yields of adipic acid are found in the case of H1.5Mn0.75PMo12O40 and (NH4)2Mn0.5PMo12O40 compounds.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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