钼钨化合物改性添加剂对MgO-Al2O3气相转化乙醇制1-丁醇催化性能的影响

IF 0.7 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Theoretical and Experimental Chemistry Pub Date : 2023-05-19 DOI:10.1007/s11237-023-09764-7

K. V. Valihura, O. V. Larina, S. O. Soloviev

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引用次数: 0

摘要

在合成过程中，通过引入钼酸盐和钨酸盐双功能添加剂，对氧化镁-氧化铝体系的氧化还原和酸碱性质进行了调控。Mo和W化合物的掺杂导致mg - al -氧化物催化剂的活性增加，乙醇缩合过程中1-丁醇生成的选择性增加，因为乙醇脱氢和乙醛缩合的位点浓度增加。

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Effect of Modifying Additives of Molybdenum and Tungsten Compounds on the Catalytic Properties of MgO-Al2O3 in the Process of Gas-Phase Conversion of Ethanol Into 1-Butanol

The regulation of redox and acid–base properties of MgO-Al₂O₃ systems has been carried out during the synthesis by introducing bifunctional additives of molybdate and tungstate ions. Doping with Mo and W compounds leads to an increase in the activity of Mg-Al-oxide catalysts and the selectivity of 1-butanol formation in the ethanol condensation process due to an increase in the concentration of the sites of ethanol dehydrogenation and acetaldehyde aldol condensation.

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来源期刊

Theoretical and Experimental Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

1.60

自引率

10.00%

发文量

审稿时长

6-12 weeks

期刊介绍： Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as: a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials; b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions; c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.