3,5-二硝基水杨酸盐与4,4'-联吡啶配体的新型2D二丁基锡配位聚合物

IF 1.8 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Main Group Metal Chemistry Pub Date : 2020-01-01 DOI:10.1515/mgmc-2020-0024

Laijin Tian, Ruili Wang, Jiawei Zhang, Qingtao Liu

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引用次数: 4

摘要

摘要合成了一种新的具有3,5-二硝基水杨酸盐和4,4’-联吡啶配体的二维二丁基锡配位聚合物，-{Bu2Sn（3,5-（NO2）2–2–OC6H2COO）}2（4,4’-bpy）]n（1），并通过光谱（IR、1H、13C和119Sn NMR）和单晶X射线衍射分析进行了表征。锡原子在1中的配位几何是一个畸变的八面体。3,5-二硝基水杨酸作为双电荷阴离子配体，采用螯合桥接模式与锡原子配位，4,4'-联吡啶进一步桥接锡原子，形成含有34元六核大环的2D人字形网络结构。

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A new 2D dibutyltin coordination polymer with 3,5-dinitrosalicylate and 4,4’-bipyridine ligands

Abstract A new 2D dibutyltin coordination polymer with 3,5-dinitrosalicylate and 4,4’-bipyridine ligands, [{Bu2Sn(3,5–(NO2)2–2–OC6H2COO)}2(4,4’-bpy)]n (1), has been synthesized and characterized both spectroscopically (IR, 1H, 13C, and 119Sn NMR) and a single-crystal X-ray diffraction analysis. The coordination geometry of tin atom in 1 is a distorted octahedron. 3,5-Dinitrosalicylate as doubly charged anion ligand adopts chelating-bridging mode to coordinate to tin atoms, and 4,4’-bipyridine further bridges the tin atoms to form a 2D herringbone-like network structure containing the 34-membered hexa-nuclear macrocycles.

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来源期刊

Main Group Metal Chemistry CHEMISTRY, INORGANIC & NUCLEAR-CHEMISTRY, ORGANIC

CiteScore

4.10

自引率

27.80%

发文量

审稿时长

4 weeks

期刊介绍： This journal is committed to the publication of short communications, original research, and review articles within the field of main group metal and semi-metal chemistry, Main Group Metal Chemistry is an open-access, peer-reviewed journal that publishes in ongoing way. Papers addressing the theoretical, spectroscopic, mechanistic and synthetic aspects of inorganic, coordination and organometallic main group metal and semi-metal compounds, including zinc, cadmium and mercury are welcome. The journal also publishes studies relating to environmental aspects of these metals, their toxicology, release pathways and fate. Articles on the applications of main group metal chemistry, including in the fields of polymer chemistry, agriculture, electronics and catalysis, are also accepted.