在最低黏合剂粘度温度下,优化复合材料成型压力和成型时间

Pub Date : 2022-04-29 DOI:10.15407/knit2022.02.003
O. Haidachuk, A. Kondratiev, A.V. Nabokina
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引用次数: 0

摘要

复合材料产品成型的工艺过程包括在一定的温度和压力下,通过粘合剂的聚合,使用形状生成成型工具使其形成不可逆的形状。本文研究了由预浸料预成型的聚合物复合材料制成的产品的最常见的成型方法的工艺参数。根据增强材料的类型,进一步发展了纤维填充密度从二次到六次变化的聚合物复合材料的增强材料纤维间空间的粘合剂填充的数学模型。提出了一种在粘合剂粘度最小的温度下优化复合材料成型压力和成型时间的新方法。该方法是通过分析相关性来实现的,该相关性在温度和时间图的截面上建立了最佳的时间间隔和成型压力,与操作设备(烘箱、高压釜)提供最大可能的温度上升速率的能力相关,以便将预浸料中的粘合剂“软化”到其最小粘度。结果表明,将聚合物复合材料的四方结构重新形成为六边形结构的能耗是四方结构形成成本的十倍。例如,将粘结剂体积含量为0.4的四方结构重新形成为致密的六边形结构需要增加66.7倍的压力。所获得的结果允许在确保复合材料产品的特定质量的同时,建立经济可行的复合材料产品成型压力和时间水平。
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Optimization of pressure and time of composite products molding at the temperature of minimum binder viscosity
The technological process of composite products’ molding consists in giving them non-a reversible shape using shape-generating molding tools through polymerization of the binder at a certain temperature and pressure varying in time. The paper deals with the research of technological parameters of the most common practical method of molding products made of polymeric composite materials, pre-formed of prepregs. The mathematical model of filling with a binder of inter-fiber space of the reinforcing material for the polymeric composite material with the varying fiber packing densities, from quadratic to hexagonal one, depending on the type of reinforcing material, has been further developed. A new method for optimization of the pressure and time of composite products’ molding at the temperature of the minimum binder viscosity has been developed. The method is implemented by analytical dependencies, which establish the optimal time intervals and pressure of molding on the section of the temperature and time diagram, associated with the ability of the operating equipment (oven, autoclave) to provide the maximum possible rate of temperature rise in order to “soften” the binder in prepreg to its minimum viscosity. It is shown that energy consumption for the re-formation of the tetragonal structure of the polymeric composite material into hexagonal one is ten times higher than the costs for the tetragonal structure formation. For example, re-formation of the tetragonal structure at volume content of the binder of 0.4 into dense hexagonal structure requires 66.7 times increase in pressure. Obtained results allow establishing the economically feasible level of pressure and time of composite products’ molding while ensuring their specified quality.
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