真空蒸馏法改善棕榈脂肪酸蒸馏生物柴油的冷流性能

IF 20.2 Q1 MATERIALS SCIENCE, PAPER & WOOD Journal of Bioresources and Bioproducts Pub Date : 2022-02-01 DOI:10.1016/j.jobab.2021.09.002
Siew Ping Yeong , Yen San Chan , Ming Chiat Law , Jordy Kim Ung Ling
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引用次数: 14

摘要

棕榈脂肪酸馏出物(PFAD)是棕榈油精制过程中的副产物,可作为生产生物柴油的潜在原料。然而,棕榈油基生物柴油的应用往往受到其较差的冷流特性(CFP)的阻碍。CFP差的生物柴油燃料可能结晶并导致燃料管路、过滤器和喷油器堵塞,从而导致发动机的可操作性问题。为此,设计了一种真空蒸馏方法,并对其改进CFP的可行性和效率进行了验证。从PFAD生物柴油中成功脱除了13.60wt%的总饱和脂肪酸甲酯,使PFAD生物柴油的浊点(CP)、冷过滤器堵塞点(CFPP)和倾点(PP)分别从20℃、19℃和15℃提高到13℃、11℃和9℃。值得注意的是,改进后的CFPP满足了EN 14212标准对温带气候C级夏季生物柴油的要求。此外,对沙林(UFAME)经验相关性进行了评估,发现它对PFAD生物柴油的CFP有很好的预测,偏差小于2°C。
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Improving cold flow properties of palm fatty acid distillate biodiesel through vacuum distillation

Palm fatty acid distillate (PFAD), a by-product of refining process of crude palm oil can be used as a potential feedstock for biodiesel production. However, the application of palm oil-based biodiesel is often hinder by its poor cold flow properties (CFP). Biodiesel fuel with poor CFP may crystallize and result in clogging of fuel lines, filters and injectors that cause engine operability problems. For that, a vacuum distillation method was designed and its feasibility and efficiency in improving the CFP was examined. A total of 13.60wt% of total saturated fatty acid methyl esters were successfully removed from the PFAD biodiesel, resulting in the improvement of the cloud point (CP), cold filter plugging point (CFPP) and pour point (PP) of PFAD biodiesel from 20 °C, 19 °C, and 15 °C to 13 °C, 11 °C, and 9 °C, respectively. It is remarkable that the improved CFPP satisfied the requirements for grade C summer biodiesel for temperate climates in EN 14212 standard. Additionally, Sarin (UFAME) empirical correlation was evaluated and it was found to have a good prediction of CFP for PFAD biodiesel, with lower than 2 °C deviation.

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来源期刊
Journal of Bioresources and Bioproducts
Journal of Bioresources and Bioproducts Agricultural and Biological Sciences-Forestry
CiteScore
39.30
自引率
0.00%
发文量
38
审稿时长
12 weeks
期刊最新文献
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