2,14双[间硝基苯基]-杯[4]间苯二酚-8,20双[N-苯基苯并]-二羟肟酸溶剂萃取、顺序分离及痕量镧、铈、钕、钆

IF 1.8 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Solvent Extraction and Ion Exchange Pub Date : 2023-05-16 DOI:10.1080/07366299.2023.2211631
C. Sharma, R. Patadia, Y. Agrawal
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引用次数: 0

摘要

摘要报道了一种新的试剂2,14-双[间硝基苯基]-杯[4]间苯二酚烯-8,20-双[N-苯基苯并]-二甲酰胺酸(NPC4RADHA),用于液-液萃取、分离和同时测定La(III)、Ce(III),Nd(Ⅲ)和Gd(III)的痕量。该方法包括优化各种参数,如NPC4RADHA的浓度、pH、溶剂和提取时间,以实现这些稀土的最大纯度(99.98%)提取。研究了稳定常数、摩尔吸光系数和比尔定律。提取的样品通过ICP-AES直接分析,提高了灵敏度,测定限为0.020 ng/mL,0.028 ng/mL,0.018 ng/mL和0.025 La、Ce、Nd和Gd分别为ng/mL。该方法已应用于独居石砂和标准地质样品中这些元素的测定。已经报道了Ce(III)和Ce(IV)的分离和测定混合物。
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Solvent Extraction, Sequential Separation and Trace Determination of La (III), Ce (III), Nd (III) and Gd (III) with 2, 14-bis[m-nitrophenyl]-Calix[4]Resorcinarene-8, 20-bis[N- phenylbenzo]-dihydroxamic Acid
ABSTRACT A novel reagent 2,14-bis[m-nitrophenyl]-calix[4]resorcinarene-8,20-bis[N-phenylbenzo]-dihydroxamic acid (NPC4RADHA) is reported for the liquid-liquid extraction, separation, and simultaneous trace determination of La(III), Ce(III), Nd(III), and Gd(III). The method involves optimizing various parameters such as the concentration of NPC4RADHA, pH, solvent, and extraction time to achieve maximum purity (99.98%) extraction of these rare earths. The stability constant, molar absorptivity, and Beer’s law have been studied. The extracted samples were directly analyzed by ICP-AES, which improves sensitivity with determination limits of 0.020 ng/mL, 0.028 ng/mL, 0.018 ng/mL and 0.025 ng/mL for La, Ce, Nd, and Gd, respectively. The method has been applied to the determination of these elements in monazite sand and standard geological samples. The separation and determination mixture of a Ce(III) and Ce(IV) has been reported.
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来源期刊
CiteScore
4.40
自引率
5.00%
发文量
15
审稿时长
8.4 months
期刊介绍: Solvent Extraction and Ion Exchange is an international journal that publishes original research papers, reviews, and notes that address all aspects of solvent extraction, ion exchange, and closely related methods involving, for example, liquid membranes, extraction chromatography, supercritical fluids, ionic liquids, microfluidics, and adsorption. We welcome submissions that look at: The underlying principles in solvent extraction and ion exchange; Solvent extraction and ion exchange process development; New materials or reagents, their syntheses and properties; Computational methods of molecular design and simulation; Advances in equipment, fluid dynamics, and engineering; Interfacial phenomena, kinetics, and coalescence; Spectroscopic and diffraction analysis of structure and dynamics; Host-guest chemistry, ion receptors, and molecular recognition.
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