{"title":"2,14双[间硝基苯基]-杯[4]间苯二酚-8,20双[N-苯基苯并]-二羟肟酸溶剂萃取、顺序分离及痕量镧、铈、钕、钆","authors":"C. Sharma, R. Patadia, Y. Agrawal","doi":"10.1080/07366299.2023.2211631","DOIUrl":null,"url":null,"abstract":"ABSTRACT A novel reagent 2,14-bis[m-nitrophenyl]-calix[4]resorcinarene-8,20-bis[N-phenylbenzo]-dihydroxamic acid (NPC4RADHA) is reported for the liquid-liquid extraction, separation, and simultaneous trace determination of La(III), Ce(III), Nd(III), and Gd(III). The method involves optimizing various parameters such as the concentration of NPC4RADHA, pH, solvent, and extraction time to achieve maximum purity (99.98%) extraction of these rare earths. The stability constant, molar absorptivity, and Beer’s law have been studied. The extracted samples were directly analyzed by ICP-AES, which improves sensitivity with determination limits of 0.020 ng/mL, 0.028 ng/mL, 0.018 ng/mL and 0.025 ng/mL for La, Ce, Nd, and Gd, respectively. The method has been applied to the determination of these elements in monazite sand and standard geological samples. The separation and determination mixture of a Ce(III) and Ce(IV) has been reported.","PeriodicalId":22002,"journal":{"name":"Solvent Extraction and Ion Exchange","volume":"41 1","pages":"606 - 626"},"PeriodicalIF":1.8000,"publicationDate":"2023-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Solvent Extraction, Sequential Separation and Trace Determination of La (III), Ce (III), Nd (III) and Gd (III) with 2, 14-bis[m-nitrophenyl]-Calix[4]Resorcinarene-8, 20-bis[N- phenylbenzo]-dihydroxamic Acid\",\"authors\":\"C. Sharma, R. Patadia, Y. Agrawal\",\"doi\":\"10.1080/07366299.2023.2211631\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT A novel reagent 2,14-bis[m-nitrophenyl]-calix[4]resorcinarene-8,20-bis[N-phenylbenzo]-dihydroxamic acid (NPC4RADHA) is reported for the liquid-liquid extraction, separation, and simultaneous trace determination of La(III), Ce(III), Nd(III), and Gd(III). The method involves optimizing various parameters such as the concentration of NPC4RADHA, pH, solvent, and extraction time to achieve maximum purity (99.98%) extraction of these rare earths. The stability constant, molar absorptivity, and Beer’s law have been studied. The extracted samples were directly analyzed by ICP-AES, which improves sensitivity with determination limits of 0.020 ng/mL, 0.028 ng/mL, 0.018 ng/mL and 0.025 ng/mL for La, Ce, Nd, and Gd, respectively. The method has been applied to the determination of these elements in monazite sand and standard geological samples. The separation and determination mixture of a Ce(III) and Ce(IV) has been reported.\",\"PeriodicalId\":22002,\"journal\":{\"name\":\"Solvent Extraction and Ion Exchange\",\"volume\":\"41 1\",\"pages\":\"606 - 626\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2023-05-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Solvent Extraction and Ion Exchange\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1080/07366299.2023.2211631\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solvent Extraction and Ion Exchange","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/07366299.2023.2211631","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Solvent Extraction, Sequential Separation and Trace Determination of La (III), Ce (III), Nd (III) and Gd (III) with 2, 14-bis[m-nitrophenyl]-Calix[4]Resorcinarene-8, 20-bis[N- phenylbenzo]-dihydroxamic Acid
ABSTRACT A novel reagent 2,14-bis[m-nitrophenyl]-calix[4]resorcinarene-8,20-bis[N-phenylbenzo]-dihydroxamic acid (NPC4RADHA) is reported for the liquid-liquid extraction, separation, and simultaneous trace determination of La(III), Ce(III), Nd(III), and Gd(III). The method involves optimizing various parameters such as the concentration of NPC4RADHA, pH, solvent, and extraction time to achieve maximum purity (99.98%) extraction of these rare earths. The stability constant, molar absorptivity, and Beer’s law have been studied. The extracted samples were directly analyzed by ICP-AES, which improves sensitivity with determination limits of 0.020 ng/mL, 0.028 ng/mL, 0.018 ng/mL and 0.025 ng/mL for La, Ce, Nd, and Gd, respectively. The method has been applied to the determination of these elements in monazite sand and standard geological samples. The separation and determination mixture of a Ce(III) and Ce(IV) has been reported.
期刊介绍:
Solvent Extraction and Ion Exchange is an international journal that publishes original research papers, reviews, and notes that address all aspects of solvent extraction, ion exchange, and closely related methods involving, for example, liquid membranes, extraction chromatography, supercritical fluids, ionic liquids, microfluidics, and adsorption. We welcome submissions that look at: The underlying principles in solvent extraction and ion exchange; Solvent extraction and ion exchange process development; New materials or reagents, their syntheses and properties; Computational methods of molecular design and simulation; Advances in equipment, fluid dynamics, and engineering; Interfacial phenomena, kinetics, and coalescence; Spectroscopic and diffraction analysis of structure and dynamics; Host-guest chemistry, ion receptors, and molecular recognition.