从稻壳和秸秆中获取生物炭

N. Appazov, B. Bazarbayev, T. Assylbekkyzy, B. Diyarova, S. A. Kanzhar, S. Magauiya, R. Zhapparbergenov, N. Akylbekov, B. Duisembekov
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引用次数: 1

摘要

本文介绍了从稻壳、秸秆等农业植物废弃物中提取生物炭的研究结果。对热解的最佳条件,如过程的持续时间和温度进行了选择。热解产物的特征在于碘吸附活性、累积水孔隙体积和体积密度。用扫描电子显微镜研究了所得产物的多孔结构。基于所进行的研究结果,已经发现从热解持续时间为30分钟的外壳和秸秆中获得的生物炭具有低的碘吸附特性和水孔隙体积。随着热解时间的增加,吸附特性得到改善,外壳在500°C的温度下的最佳热解时间为60分钟,秸秆在300°C的条件下的最佳热分解时间为60 min。最佳选择是在60分钟的时间和300°C的热解温度下从稻草中获得的生物炭,其碘吸附活性为54.61%,累积气孔体积为0.941 cm3/g,堆积密度为169.29 g/dm3。用4300倍和5000倍的扫描电子显微镜研究了从稻壳和稻草中获得的生物炭,它们具有发达的多孔结构。根据文献,已知生物炭也可以用作可再生能源。已经进行了研究以确定所获得的生物炭的热值。为了比较稻壳、秸秆和所获得的生物炭的热值,在量热计上测定了它们的热值。从壳中获得的生物炭的最高热值为60分钟,在400°C的热解温度下为17.520 kJ/g,从秸秆中获得的最佳热值为60 min,在400℃的热解温度为16.451 kJ/g。所获得的实验数据使将来使用从稻草中获得的生物炭作为生物肥料来改善土壤特性成为可能,也使使用从稻壳中获得的生化炭来生产可再生燃料成为可能。
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OBTAINING BIOCHAR FROM RICE HUSK AND STRAW
This paper presents the results of research on obtaining biochar from agricultural plant waste such as rice husk and straw. The selection of the optimal conditions for thermolysis, such as the duration and temperature of the process, has been conducted. The thermolysis products are characterized for iodine adsorption activity, cumulative water pore volume, and for bulk density. The porous structure of the obtained products has been studied by scanning electron microscopy. Based on the results of the research conducted, it has been found that biochars obtained from husk and straw with a thermolysis duration of 30 minutes have low iodine sorption characteristics and water pore volumes. With an increase in the duration of thermolysis, the sorption characteristics improve, the optimal for the husk is the thermolysis duration of 60 minutes at a temperature of 500°C, and for straw, the optimal thermolysis duration is 60 minutes at a temperature of 300°C. The best option is biochar obtained from rice straw at a duration of 60 minutes and a thermolysis temperature of 300°C, having an iodine adsorption activity of 54.61%, a cumulative water pore volume of 0.941 cm3/g and a bulk density of 169.29 g/dm3. The obtained biochars from rice husk and straw have been studied by scanning electron microscopy at 4300 and 5000 times magnification, and they have a developed porous structure. According to the literature, it is known that biochar can also be used as a renewable energy source. Research has been carried out to determine the calorific value of the obtained biochars. To compare the calorific value of rice husk, straw and the obtained biochars, their heating values have been determined on a calorimeter. The highest heating value has a biochar obtained from husk at a duration of 60 minutes and at a thermolysis temperature of 400°C with a value of 17.520 kJ/g, the optimal for biochar obtained from straw is a duration of 60 minutes and a thermolysis temperature of 400°C with a value of 16.451 kJ/g. The experimental data obtained make it possible to use the obtained biochar from rice straw in the future as a biofertilizer to improve the characteristics of soils, as well as to use biochar obtained from rice husk to produce renewable fuel.
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