用声化学法由硫酸锌加速有效合成硼酸锌

IF 1.8 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Main Group Metal Chemistry Pub Date : 2020-01-01 DOI:10.1515/mgmc-2020-0002
A. Ersan, A. Kipcak, Meral Yildirim Ozen, N. Tugrul
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引用次数: 8

摘要

摘要近年来,声化学已被用于合成无机化合物,如硼酸锌。本研究以七水硫酸锌(ZnSO4·7H2O)和硼酸(H3BO3)为原料,用超声波探针合成了Zn3B6O12·3.5H2O形式的硼酸锌化合物。利用X射线衍射(XRD)、扫描电子显微镜(SEM)、傅立叶变换红外光谱(FT-IR)和拉曼光谱对产物进行了表征。用拉曼光谱和红外光谱观察了硼酸锌化合物的化学键结构。从XRD结果可以看出,在80°C和85°C(55分钟)或90°C(45分钟)下加热可以快速合成Zn3B6O12·3.5H2O,产率非常高(>90%)。根据SEM结果,获得的最小颗粒尺寸为~143μm。硼酸锌化合物的合成温度较低,合成时间较短。
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An accelerated and effective synthesis of zinc borate from zinc sulfate using sonochemistry
Abstract Recently, sonochemistry has been used for the synthesis of inorganic compounds, such as zinc borates. In this study using zinc sulphate heptahydrate (ZnSO4·7H2O) and boric acid (H3BO3) as starting materials, a zinc borate compound in the form of Zn3B6O12·3.5H2O was synthesized using an ultrasonic probe. Product’s characterization was carried out with using X-ray diffraction (XRD), Scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FT-IR) and Raman spectroscopy. Zinc borate compound’s chemical bond structure was observed with Raman and FTIR. From the XRD results it was seen that Zn3B6O12·3.5H2O can be quickly synthesized upon heating at 80°C and 85°C (55 min) or 90°C (45 min) in very high yield (>90%). The minimum particle size obtained was ~143 μm from the SEM results. Zinc borate compound was synthesized at a lower temperature in less time than other synthesized zinc metal compound in literature.
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来源期刊
Main Group Metal Chemistry
Main Group Metal Chemistry CHEMISTRY, INORGANIC & NUCLEAR-CHEMISTRY, ORGANIC
CiteScore
4.10
自引率
27.80%
发文量
21
审稿时长
4 weeks
期刊介绍: This journal is committed to the publication of short communications, original research, and review articles within the field of main group metal and semi-metal chemistry, Main Group Metal Chemistry is an open-access, peer-reviewed journal that publishes in ongoing way. Papers addressing the theoretical, spectroscopic, mechanistic and synthetic aspects of inorganic, coordination and organometallic main group metal and semi-metal compounds, including zinc, cadmium and mercury are welcome. The journal also publishes studies relating to environmental aspects of these metals, their toxicology, release pathways and fate. Articles on the applications of main group metal chemistry, including in the fields of polymer chemistry, agriculture, electronics and catalysis, are also accepted.
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