A. V. Bykov, L. Zh. Nikoshvili, G. N. Demidenko, M. G. Sul’man, L. Kiwi-Minsker
{"title":"贵金属在超交联聚苯乙烯聚合物基体中的浸渍","authors":"A. V. Bykov, L. Zh. Nikoshvili, G. N. Demidenko, M. G. Sul’man, L. Kiwi-Minsker","doi":"10.1134/S2070050422020027","DOIUrl":null,"url":null,"abstract":"<p>Commercial super cross-linked polystyrene (SPS) is a promising support for creating heterogeneous catalysts designed for processes of fine organic synthesis. Results from years of studying the creation of heterogeneous Pd-, Pt-, and Ru-containing catalysts based on SPS of grades MN100 and MN270. Data are presented from characterizing SPS and catalysts based on them using a complex of physical and physicochemical means of analysis. It is shown that commercial SPS can be used to synthesize catalysts in the form of spherical grains or preliminarily ground powders. Along with the nature of a metal catalyst precursor, the form of an SPS has a strong effect on the distribution of Pd, Pt, and Ru compounds and the size of metal-containing nanoparticles formed in the polymer’s medium. The catalysts in a hydrogen flow at a temperature of 300°C on the surface chemical composition of powder MN100 samples impregnated w Pd, Pt, and Ru compounds is considered for the first time.</p>","PeriodicalId":507,"journal":{"name":"Catalysis in Industry","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2022-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Impregnating Noble Metals into the Polymer Matrix of Super Cross-Linked Polystyrene\",\"authors\":\"A. V. Bykov, L. Zh. Nikoshvili, G. N. Demidenko, M. G. Sul’man, L. Kiwi-Minsker\",\"doi\":\"10.1134/S2070050422020027\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Commercial super cross-linked polystyrene (SPS) is a promising support for creating heterogeneous catalysts designed for processes of fine organic synthesis. Results from years of studying the creation of heterogeneous Pd-, Pt-, and Ru-containing catalysts based on SPS of grades MN100 and MN270. Data are presented from characterizing SPS and catalysts based on them using a complex of physical and physicochemical means of analysis. It is shown that commercial SPS can be used to synthesize catalysts in the form of spherical grains or preliminarily ground powders. Along with the nature of a metal catalyst precursor, the form of an SPS has a strong effect on the distribution of Pd, Pt, and Ru compounds and the size of metal-containing nanoparticles formed in the polymer’s medium. The catalysts in a hydrogen flow at a temperature of 300°C on the surface chemical composition of powder MN100 samples impregnated w Pd, Pt, and Ru compounds is considered for the first time.</p>\",\"PeriodicalId\":507,\"journal\":{\"name\":\"Catalysis in Industry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2022-06-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis in Industry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S2070050422020027\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis in Industry","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S2070050422020027","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Impregnating Noble Metals into the Polymer Matrix of Super Cross-Linked Polystyrene
Commercial super cross-linked polystyrene (SPS) is a promising support for creating heterogeneous catalysts designed for processes of fine organic synthesis. Results from years of studying the creation of heterogeneous Pd-, Pt-, and Ru-containing catalysts based on SPS of grades MN100 and MN270. Data are presented from characterizing SPS and catalysts based on them using a complex of physical and physicochemical means of analysis. It is shown that commercial SPS can be used to synthesize catalysts in the form of spherical grains or preliminarily ground powders. Along with the nature of a metal catalyst precursor, the form of an SPS has a strong effect on the distribution of Pd, Pt, and Ru compounds and the size of metal-containing nanoparticles formed in the polymer’s medium. The catalysts in a hydrogen flow at a temperature of 300°C on the surface chemical composition of powder MN100 samples impregnated w Pd, Pt, and Ru compounds is considered for the first time.
期刊介绍：
The journal covers the following topical areas:
Analysis of specific industrial catalytic processes: Production and use of catalysts in branches of industry: chemical, petrochemical, oil-refining, pharmaceutical, organic synthesis, fuel-energetic industries, environment protection, biocatalysis; technology of industrial catalytic processes (generalization of practical experience, improvements, and modernization); technology of catalysts production, raw materials and equipment; control of catalysts quality; starting, reduction, passivation, discharge, storage of catalysts; catalytic reactors.Theoretical foundations of industrial catalysis and technologies: Research, studies, and concepts : search for and development of new catalysts and new types of supports, formation of active components, and mechanochemistry in catalysis; comprehensive studies of work-out catalysts and analysis of deactivation mechanisms; studies of the catalytic process at different scale levels (laboratory, pilot plant, industrial); kinetics of industrial and newly developed catalytic processes and development of kinetic models; nonlinear dynamics and nonlinear phenomena in catalysis: multiplicity of stationary states, stepwise changes in regimes, etc. Advances in catalysis: Catalysis and gas chemistry; catalysis and new energy technologies; biocatalysis; nanocatalysis; catalysis and new construction materials.History of the development of industrial catalysis.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
