介源镝(III)配合物与向列液晶混合物的热力学和光学性质

IF 0.3 Q4 CRYSTALLOGRAPHY Liquid Crystals and their Application Pub Date : 2021-06-29 DOI:10.18083/lcappl.2021.2.45
M. E. Karyakin, A. Kovshik, A. Krupin, L. Dobrun, A. Knyazev, Y. Galyametdinov
{"title":"介源镝(III)配合物与向列液晶混合物的热力学和光学性质","authors":"M. E. Karyakin, A. Kovshik, A. Krupin, L. Dobrun, A. Knyazev, Y. Galyametdinov","doi":"10.18083/lcappl.2021.2.45","DOIUrl":null,"url":null,"abstract":"In this regard, a practically important task is to obtain lanthanide-containing liquid crystal systems exhibiting nematic mesomorphism in a wide temperature range. Therefore, in this work, we have demonstrated the possibility of creating homogeneous nematic mixtures based on the synthesized paramagnetic liquid crystal 5,5'-diheptadecyl-2,2'-bipyridine dysprosium (III) complex with liquid crystal 1-(4-fluorophenyl)-3-(4-(4-propylcyclohexyl)phe-nyl)propane-1,3-dione. The latest possesses wide mesophase range and low crystallization temperature. The phase diagrams of the studied mixtures were constructed using the data of polarizing optical microscopy and differential scanning calorimetry. Their thermodynamic and optical characteristics (main values of refractive indices, optical anisotropy, degree of orientational order) have been studied.","PeriodicalId":18138,"journal":{"name":"Liquid Crystals and their Application","volume":" ","pages":""},"PeriodicalIF":0.3000,"publicationDate":"2021-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Thermodynamic and Optical Properties of Mixtures Based on Mesogenic Dysprosium (III) Complex and Nematic Liquid Crystal\",\"authors\":\"M. E. Karyakin, A. Kovshik, A. Krupin, L. Dobrun, A. Knyazev, Y. Galyametdinov\",\"doi\":\"10.18083/lcappl.2021.2.45\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this regard, a practically important task is to obtain lanthanide-containing liquid crystal systems exhibiting nematic mesomorphism in a wide temperature range. Therefore, in this work, we have demonstrated the possibility of creating homogeneous nematic mixtures based on the synthesized paramagnetic liquid crystal 5,5'-diheptadecyl-2,2'-bipyridine dysprosium (III) complex with liquid crystal 1-(4-fluorophenyl)-3-(4-(4-propylcyclohexyl)phe-nyl)propane-1,3-dione. The latest possesses wide mesophase range and low crystallization temperature. The phase diagrams of the studied mixtures were constructed using the data of polarizing optical microscopy and differential scanning calorimetry. Their thermodynamic and optical characteristics (main values of refractive indices, optical anisotropy, degree of orientational order) have been studied.\",\"PeriodicalId\":18138,\"journal\":{\"name\":\"Liquid Crystals and their Application\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.3000,\"publicationDate\":\"2021-06-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Liquid Crystals and their Application\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.18083/lcappl.2021.2.45\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CRYSTALLOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Liquid Crystals and their Application","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.18083/lcappl.2021.2.45","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
引用次数: 0

摘要

在这方面,一个实际重要的任务是获得在宽温度范围内表现出向列介晶性的含镧系元素的液晶系统。因此,在这项工作中,我们已经证明了基于合成的顺磁性液晶5,5'-二十七烷基-2,2'-联吡啶镝(III)与液晶1-(4-氟苯基)-3-(4-(4-丙基环己基)苯基)丙烷-1,3-二酮的络合物产生均匀向列混合物的可能性。最新的具有较宽的中间相范围和较低的结晶温度。利用偏光显微镜和差示扫描量热法的数据构建了所研究混合物的相图。研究了它们的热力学和光学特性(折射率、光学各向异性、取向有序度的主要值)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Thermodynamic and Optical Properties of Mixtures Based on Mesogenic Dysprosium (III) Complex and Nematic Liquid Crystal
In this regard, a practically important task is to obtain lanthanide-containing liquid crystal systems exhibiting nematic mesomorphism in a wide temperature range. Therefore, in this work, we have demonstrated the possibility of creating homogeneous nematic mixtures based on the synthesized paramagnetic liquid crystal 5,5'-diheptadecyl-2,2'-bipyridine dysprosium (III) complex with liquid crystal 1-(4-fluorophenyl)-3-(4-(4-propylcyclohexyl)phe-nyl)propane-1,3-dione. The latest possesses wide mesophase range and low crystallization temperature. The phase diagrams of the studied mixtures were constructed using the data of polarizing optical microscopy and differential scanning calorimetry. Their thermodynamic and optical characteristics (main values of refractive indices, optical anisotropy, degree of orientational order) have been studied.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
1.30
自引率
40.00%
发文量
30
期刊介绍: The Journal presents the following main directions of creation/construction, study and application of self-assembled materials: SYNTHESIS, STRUCTURE, PROPERTIES, MEDICINE, BIOLOGY, NANOTECHNOLOGY, SENSORS, PRACTICAL APPLICATION and INFORMATION. The journal is addressed to researchers, lecturers, university students, engineers. The publisher of the journal is the Nanomaterials Research Institute of "Ivanovo State University".
期刊最新文献
Stability of Nano-Sized Aqueous Dispersion of n-Heptadecane to Thermal Cycling Liquid Crystalline Electro-Optical Modulator of Submegahertz Range Wetting and Adhesive Properties of Biopolymer-Based Organized Condensed Phases as Drug Delivery Systems Non-Newtonian Flow of Structured Systems. XXXVII. Viscoelasticity of Clay / Nylon-11 Polymer Composite Influence of Design Parameters of Liquid Crystal Cell on the Optical Threshold Voltage Value of Electro-Optical Effect
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1