自由基n、o和o3对电晕放电中氮氧化物还原的影响

A. Ferouani, M. Lemerini, M. Sahlaoui, S. Askri, Mokhtar Khaldi, Y. Boumellah
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引用次数: 0

摘要

本文介绍了常温常压下直流电晕放电对氮氧混合气体中不同物质的化学动力学分析。这项研究考虑了20种不同的化学物质在150种选定的化学反应后的反应。反应速率系数取自文献,密度用不含扩散项的连续性方程进行分析。许多研究都表明了N、O和O3自由基对去除NOx的作用。因此,本仿真的目的是通过分析100- 200td不同电场下的各种等离子体种类来完成这些研究。我们特别分析了氮氧化物的减少速率演化(10-9 - 10-3 s)。我们发现,从初始值100Td上升到200Td,电场的减小对NO和NO2的减少速率有很大的影响。因此,我们在模拟中得到100Td的NO去除率为2%,而200Td的去除率为96%。这使我们知道了约化电场所起的重要作用。
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THE INFLUENCE OF RADICAL N, O AND O3 IN THE REDUCTION OF NITROGEN OXIDES IN A CORONA DISCHARGE
This work presents a chemical kinetic analysis of different species involved in nitrogen-oxygen mixed gas by a DC (Corona Discharge) at room temperature and atmospheric pressure. This study takes into account 20 different chemical species reacting following 150 selected chemicals reactions. The reaction rate coefficients are taken from the literature and the density is analyzed by the continuity equation without the diffusion term. Many works have study removal NOx and they have showing the role of N, O and O3 radicals. So the aim of this simulation is to complete these studies by analyse of various plasma species under different reduced electric field: 100-200 Td. We analyse especially, the temporal depopulation rate evolution (10-9 – 10-3 s) of NOx. We have found that the rate depopulation of NO and NO2 is substantially affected by the reduced electric field rise from the initial value of 100Td up to 200Td. Thus, we have obtained in our simulation 2% of NO removal for 100Td against 96% for 200Td. This allows us the important role played by the reduced electric field.
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