N. V. Gromov, T. B. Medvedeva, V. N. Panchenko, O. P. Taran, M. N. Timofeeva, V. N. Parmon
{"title":"双功能催化剂Ru/Сs3HSiW12O40催化马铃薯淀粉一锅水解加氢制山梨醇","authors":"N. V. Gromov, T. B. Medvedeva, V. N. Panchenko, O. P. Taran, M. N. Timofeeva, V. N. Parmon","doi":"10.1134/S207005042301004X","DOIUrl":null,"url":null,"abstract":"<p>The possibility of obtaining sorbitol from potato starch via one-pot hydrolysis-hydrogenation is demonstrated using bifunctional catalysts 0.3–3 wt % Ru/Cs<sub>3</sub>HSiW<sub>12</sub>O<sub>40</sub> (Ru/Cs-HPA). It is found that a catalyst with 1 wt % Ru is the one most effective, since it has the optimum ratio of the concentrations of Brønsted and Lewis acid sites on the support’s surface and a large specific surface area. The kinetics of the reaction with 1% Ru/Cs-HPA is studied and the observed energy of activation of the hydrolysis-hydrogenation of starch to sorbitol is found to be 80 ± 8 kJ/mol. A kinetic model is proposed on the basis of experimental and published data. The model accurately describes the hydrolysis-hydrogenation of starch. The yield of sorbitol was 88 mol % (99 wt %) after 3 hours of the reaction using a catalyst with the optimum composition (1% Ru/Cs-HPA) at the optimum temperature (150°C).</p>","PeriodicalId":507,"journal":{"name":"Catalysis in Industry","volume":"15 1","pages":"87 - 98"},"PeriodicalIF":1.3000,"publicationDate":"2023-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"One-Pot Hydrolysis-Hydrogenation of Potato Starch to Sorbitol Using Bifunctional Catalyst Ru/Сs3HSiW12O40\",\"authors\":\"N. V. Gromov, T. B. Medvedeva, V. N. Panchenko, O. P. Taran, M. N. Timofeeva, V. N. Parmon\",\"doi\":\"10.1134/S207005042301004X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The possibility of obtaining sorbitol from potato starch via one-pot hydrolysis-hydrogenation is demonstrated using bifunctional catalysts 0.3–3 wt % Ru/Cs<sub>3</sub>HSiW<sub>12</sub>O<sub>40</sub> (Ru/Cs-HPA). It is found that a catalyst with 1 wt % Ru is the one most effective, since it has the optimum ratio of the concentrations of Brønsted and Lewis acid sites on the support’s surface and a large specific surface area. The kinetics of the reaction with 1% Ru/Cs-HPA is studied and the observed energy of activation of the hydrolysis-hydrogenation of starch to sorbitol is found to be 80 ± 8 kJ/mol. A kinetic model is proposed on the basis of experimental and published data. The model accurately describes the hydrolysis-hydrogenation of starch. The yield of sorbitol was 88 mol % (99 wt %) after 3 hours of the reaction using a catalyst with the optimum composition (1% Ru/Cs-HPA) at the optimum temperature (150°C).</p>\",\"PeriodicalId\":507,\"journal\":{\"name\":\"Catalysis in Industry\",\"volume\":\"15 1\",\"pages\":\"87 - 98\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2023-05-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis in Industry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S207005042301004X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis in Industry","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S207005042301004X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
One-Pot Hydrolysis-Hydrogenation of Potato Starch to Sorbitol Using Bifunctional Catalyst Ru/Сs3HSiW12O40
The possibility of obtaining sorbitol from potato starch via one-pot hydrolysis-hydrogenation is demonstrated using bifunctional catalysts 0.3–3 wt % Ru/Cs3HSiW12O40 (Ru/Cs-HPA). It is found that a catalyst with 1 wt % Ru is the one most effective, since it has the optimum ratio of the concentrations of Brønsted and Lewis acid sites on the support’s surface and a large specific surface area. The kinetics of the reaction with 1% Ru/Cs-HPA is studied and the observed energy of activation of the hydrolysis-hydrogenation of starch to sorbitol is found to be 80 ± 8 kJ/mol. A kinetic model is proposed on the basis of experimental and published data. The model accurately describes the hydrolysis-hydrogenation of starch. The yield of sorbitol was 88 mol % (99 wt %) after 3 hours of the reaction using a catalyst with the optimum composition (1% Ru/Cs-HPA) at the optimum temperature (150°C).
期刊介绍：
The journal covers the following topical areas:
Analysis of specific industrial catalytic processes: Production and use of catalysts in branches of industry: chemical, petrochemical, oil-refining, pharmaceutical, organic synthesis, fuel-energetic industries, environment protection, biocatalysis; technology of industrial catalytic processes (generalization of practical experience, improvements, and modernization); technology of catalysts production, raw materials and equipment; control of catalysts quality; starting, reduction, passivation, discharge, storage of catalysts; catalytic reactors.Theoretical foundations of industrial catalysis and technologies: Research, studies, and concepts : search for and development of new catalysts and new types of supports, formation of active components, and mechanochemistry in catalysis; comprehensive studies of work-out catalysts and analysis of deactivation mechanisms; studies of the catalytic process at different scale levels (laboratory, pilot plant, industrial); kinetics of industrial and newly developed catalytic processes and development of kinetic models; nonlinear dynamics and nonlinear phenomena in catalysis: multiplicity of stationary states, stepwise changes in regimes, etc. Advances in catalysis: Catalysis and gas chemistry; catalysis and new energy technologies; biocatalysis; nanocatalysis; catalysis and new construction materials.History of the development of industrial catalysis.
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