PtP2X2（X=As、Ge或Te）衍生物中的有机二膦-结构方面

IF 1.8 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Main Group Metal Chemistry Pub Date : 2020-01-01 DOI:10.1515/mgmc-2020-0016

M. Melnik, P. Mikuš

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引用次数: 4

摘要

对顺式Pt（η2-P2L）（XL）2（X=Ge或Te）、顺式Pt（η2-P2L）（η2-X2L）（X=As，Ge或Te）和反式Pt的结构数据进行了分类和分析。螯合配体产生各种金属环，其开口顺序为：83.1°（GeGeGe）<83.8°（AsC2As）<86.2°（PC2P）<88.5°（PC2Te）<89.7°（PC3P）~89.7°（GeGe2Ge）。将结构数据与内配位球Pt（η2-P2L）（XL）2（X=O，N，CN，B，Cl，S，Se，Si，Br或I）、Pt。

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Organodiphosphines in PtP2X2 (X = As, Ge or Te) derivatives – Structural aspects

Abstract Structural data of cis-Pt(η2-P2L)(XL)2 (X = Ge or Te), cis-Pt(η2-P2L)(η2-X2L) (X = As, Ge or Te) and trans-Pt(η2-P,TeL)2 were classified and analyzed. The chelating ligands create varieties of metallocyclic rings, which open in the sequence: 83.1° (GeGeGe) < 83.8° (AsC2As) < 86.2° (PC2P) < 88.5° (PC2Te) < 89.7° (PC3P) ~ 89.7° (GeGe2Ge). The structural data are compared and discussed with the complexes of an inner coordination spheres Pt(η2-P2L)(XL)2 (X = O, N, CN, B, Cl, S, Se, Si, Br or I), Pt(η2-P2L)(η2- X2L) (X = O, N, S, Se or Si), and Pt(η2-P,SiL)2.

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来源期刊

Main Group Metal Chemistry CHEMISTRY, INORGANIC & NUCLEAR-CHEMISTRY, ORGANIC

CiteScore

4.10

自引率

27.80%

发文量

审稿时长

4 weeks

期刊介绍： This journal is committed to the publication of short communications, original research, and review articles within the field of main group metal and semi-metal chemistry, Main Group Metal Chemistry is an open-access, peer-reviewed journal that publishes in ongoing way. Papers addressing the theoretical, spectroscopic, mechanistic and synthetic aspects of inorganic, coordination and organometallic main group metal and semi-metal compounds, including zinc, cadmium and mercury are welcome. The journal also publishes studies relating to environmental aspects of these metals, their toxicology, release pathways and fate. Articles on the applications of main group metal chemistry, including in the fields of polymer chemistry, agriculture, electronics and catalysis, are also accepted.