熔融纺丝过程中聚合物纤维直径的预测模型

IF 4.6 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2023-03-23 DOI:10.1155/2023/7983819
Alexander M. Bier, Michael Redel, D. Schubert
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引用次数: 0

摘要

对聚合物材料的可纺性和各自的纤维直径进行了评估。首先使用改进的单纤维纺丝装置推导出一个新的通用模型,利用工艺参数(模头直径、产量和拉伸相关的卷取压力)和材料特性(零剪切粘度)来预测基于四种不同聚合物的聚合物纤维的直径。对通过常规熔融纺丝和熔喷工艺生产的长丝进行了所得幂律依赖性的进一步评估。在试验机上生产的纤维与模型方程非常一致,只需要调整一个易于计算的设备相关因素。所提出的工作的结果是一个具有高度实际相关性的用户友好模型,该模型可用于预测无定形和半结晶聚合物纤维的直径,与所使用的材料和机器无关,具有足够的精度以进行快速估计。
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Model to Predict Polymer Fibre Diameter during Melt Spinning
Polymeric materials were evaluated with regard to their spinnability and respective fibre diameters. A modified single fibre spinning device was firstly used to derive a novel generalised model, utilising process parameters (die diameter, throughput, and stretching relevant take-up pressures) and material properties (zero shear viscosity) to predict the diameter of polymeric fibres on the basis of four different polymers. Further evaluation of the resulting power law dependence was conducted on filaments produced via conventional melt spinning and meltblown processes. Fibres produced on the pilot machines showed close agreement with the model equation with only the need to adjust an easily calculable device dependent factor. The outcome of the presented work is a user-friendly model of high practical relevance, which can be used to predict the diameter of amorphous and semicrystalline polymeric fibres, independent of material and machine used with sufficient accuracy for fast estimations.
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
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