{"title":"层状双氢氧化物存在下的环氧丙烷聚合","authors":"Olena Dan, E. Butenko, A. Kapustin","doi":"10.1515/cdem-2018-0009","DOIUrl":null,"url":null,"abstract":"Abstract Propylene oxide polymerization in the presence of layered double hydroxides with different concentration of basic sites on their surface has been studied. It is shown that the polymerization can be catalyzed by both basic and acidic sites. On the basis of kinetic experiments the mechanisms of reaction undergoing were proposed.","PeriodicalId":41079,"journal":{"name":"Chemistry-Didactics-Ecology-Metrology","volume":"23 1","pages":"137 - 142"},"PeriodicalIF":0.7000,"publicationDate":"2018-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Propylene Oxide Polymerization in the Presence of Layered Double Hydroxides\",\"authors\":\"Olena Dan, E. Butenko, A. Kapustin\",\"doi\":\"10.1515/cdem-2018-0009\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Propylene oxide polymerization in the presence of layered double hydroxides with different concentration of basic sites on their surface has been studied. It is shown that the polymerization can be catalyzed by both basic and acidic sites. On the basis of kinetic experiments the mechanisms of reaction undergoing were proposed.\",\"PeriodicalId\":41079,\"journal\":{\"name\":\"Chemistry-Didactics-Ecology-Metrology\",\"volume\":\"23 1\",\"pages\":\"137 - 142\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2018-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry-Didactics-Ecology-Metrology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1515/cdem-2018-0009\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MULTIDISCIPLINARY SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry-Didactics-Ecology-Metrology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/cdem-2018-0009","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MULTIDISCIPLINARY SCIENCES","Score":null,"Total":0}
Propylene Oxide Polymerization in the Presence of Layered Double Hydroxides
Abstract Propylene oxide polymerization in the presence of layered double hydroxides with different concentration of basic sites on their surface has been studied. It is shown that the polymerization can be catalyzed by both basic and acidic sites. On the basis of kinetic experiments the mechanisms of reaction undergoing were proposed.
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