{"title":"不同金属氧化物对PbO-CdO-SiO2-B2O3-Al2O3体系玻璃理化性质的影响","authors":"N. S. Lozinskii, Ya. A. Moroz, A. N. Lopanov","doi":"10.1134/S1087659622601101","DOIUrl":null,"url":null,"abstract":"<p>The physicochemical processes occurring in glasses of the PbO–CdO–SiO<sub>2</sub>–B<sub>2</sub>O<sub>3</sub>–Al<sub>2</sub>O<sub>3</sub> system after high-temperature contact with oxides of various metals—CuO, NiO, Al<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, Nb<sub>2</sub>O<sub>5</sub>, and WO<sub>3</sub>, as well as the electrical resistance of the obtained glasses—are studied by X-ray phase analysis, infrared spectroscopy, and electron paramagnetic resonance. It is established that these properties are determined by the acid-base and redox properties of the oxides and glasses, which directly depend on the content of the O<sup>2–</sup> ion in each specific composition.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2023-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of Oxides of Various Metals on the Physicochemical Properties of Glass in the PbO–CdO–SiO2–B2O3–Al2O3 System\",\"authors\":\"N. S. Lozinskii, Ya. A. Moroz, A. N. Lopanov\",\"doi\":\"10.1134/S1087659622601101\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The physicochemical processes occurring in glasses of the PbO–CdO–SiO<sub>2</sub>–B<sub>2</sub>O<sub>3</sub>–Al<sub>2</sub>O<sub>3</sub> system after high-temperature contact with oxides of various metals—CuO, NiO, Al<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, Nb<sub>2</sub>O<sub>5</sub>, and WO<sub>3</sub>, as well as the electrical resistance of the obtained glasses—are studied by X-ray phase analysis, infrared spectroscopy, and electron paramagnetic resonance. It is established that these properties are determined by the acid-base and redox properties of the oxides and glasses, which directly depend on the content of the O<sup>2–</sup> ion in each specific composition.</p>\",\"PeriodicalId\":580,\"journal\":{\"name\":\"Glass Physics and Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2023-05-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Glass Physics and Chemistry\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1087659622601101\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Glass Physics and Chemistry","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S1087659622601101","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Effect of Oxides of Various Metals on the Physicochemical Properties of Glass in the PbO–CdO–SiO2–B2O3–Al2O3 System
The physicochemical processes occurring in glasses of the PbO–CdO–SiO2–B2O3–Al2O3 system after high-temperature contact with oxides of various metals—CuO, NiO, Al2O3, TiO2, Nb2O5, and WO3, as well as the electrical resistance of the obtained glasses—are studied by X-ray phase analysis, infrared spectroscopy, and electron paramagnetic resonance. It is established that these properties are determined by the acid-base and redox properties of the oxides and glasses, which directly depend on the content of the O2– ion in each specific composition.
期刊介绍：
Glass Physics and Chemistry presents results of research on the inorganic and physical chemistry of glass, ceramics, nanoparticles, nanocomposites, and high-temperature oxides and coatings. The journal welcomes manuscripts from all countries in the English or Russian language.
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