Maria Edith Casacchia, G. Giorgianni, E. Allegritti, L. Giansanti, Armando Carlone, Fabio Pesciaioli
{"title":"胶束催化下掩蔽乙醛有机催化合成γ-氨基酸前体","authors":"Maria Edith Casacchia, G. Giorgianni, E. Allegritti, L. Giansanti, Armando Carlone, Fabio Pesciaioli","doi":"10.1055/a-1996-8940","DOIUrl":null,"url":null,"abstract":"The development of micellar catalysis offers a sustainable alternative to organic solvents representing an environmental milestone in organic synthesis. Here the first Michael addition of masked acetaldehyde under neutral, cationic and anionic micellar catalysis is reported, affording the products in high yields and enantiomeric excess in spite the use of water as solvent.","PeriodicalId":22135,"journal":{"name":"SynOpen","volume":null,"pages":null},"PeriodicalIF":2.0000,"publicationDate":"2022-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Organocatalytic Synthesis of γ-Amino Acid Precursors via Masked Acetaldehyde under Micellar Catalysis\",\"authors\":\"Maria Edith Casacchia, G. Giorgianni, E. Allegritti, L. Giansanti, Armando Carlone, Fabio Pesciaioli\",\"doi\":\"10.1055/a-1996-8940\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The development of micellar catalysis offers a sustainable alternative to organic solvents representing an environmental milestone in organic synthesis. Here the first Michael addition of masked acetaldehyde under neutral, cationic and anionic micellar catalysis is reported, affording the products in high yields and enantiomeric excess in spite the use of water as solvent.\",\"PeriodicalId\":22135,\"journal\":{\"name\":\"SynOpen\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.0000,\"publicationDate\":\"2022-11-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"SynOpen\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1055/a-1996-8940\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"SynOpen","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1055/a-1996-8940","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Organocatalytic Synthesis of γ-Amino Acid Precursors via Masked Acetaldehyde under Micellar Catalysis
The development of micellar catalysis offers a sustainable alternative to organic solvents representing an environmental milestone in organic synthesis. Here the first Michael addition of masked acetaldehyde under neutral, cationic and anionic micellar catalysis is reported, affording the products in high yields and enantiomeric excess in spite the use of water as solvent.
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