改性活性炭表面处理水溶液中有机污染物

IF 2.4 Q3 CHEMISTRY, MULTIDISCIPLINARY Moroccan Journal of Chemistry Pub Date : 2020-08-05 DOI:10.48317/IMIST.PRSM/MORJCHEM-V8I4.21728
L. Mahardiani, Andri Ashadi, S. Saputro, N. Y. Indriyanti, M. Taufiq
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引用次数: 1

摘要

利用改性活性炭表面对水溶液中的有机污染物进行了去除。采用化学和物理处理方法,如分别使用氧化剂(HNO3)和空气氧化对活性炭进行改性。本研究以罗丹明B为有机污染物。结果表明,经空气氧化处理的活性炭在接触30分钟后迅速达到对罗丹明B的吸附。吸附数据用于模拟,来自伪一阶和伪二阶动力学方程以及颗粒内扩散模型。若丹明B的等温线吸附与Freundlich等温线拟合,表明吸附通过多层吸附机制发生在非均相表面上。此外,颗粒内扩散表明,有两个阶段的机制有助于罗丹明B的吸附效率。
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The Removal of Organic Pollutant from Aqueous Solution by Modified Activated Carbon Surface
The removal of organic pollutant from aqueous solution was carried out by using modified activated carbon surface. Activated carbon was modified using chemical and physical treatment, such as using oxidizing agent (HNO 3 ) and air oxidation, respectively. In this study, Rhodamine B was used as the organic pollutant. The results showed that activated carbon modified with air oxidation treatment rapidly attained the Rhodamine B adsorption after 30 minutes of contact time. Adsorption data are used for modelling, from the pseudo-first-order and pseudo-second-order kinetic equation and intra-particle diffusion models. The isotherm adsorption of Rhodamine B was fitted with Freundlich isotherm indicating that adsorption occurs on a heterogeneous surface through a multilayer adsorption mechanism. In addition, the intra-particle diffusion suggests that there were two stage mechanisms which contributed to the adsorption efficiency of Rhodamine B.
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来源期刊
Moroccan Journal of Chemistry
Moroccan Journal of Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
3.40
自引率
9.10%
发文量
0
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