纳米填料分散对环氧-氧化铝纳米复合材料电学和力学性能的影响

Neelmani, R. Sarathi, H. Suematsu, Toshikatsu Tanaka
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引用次数: 0

摘要

环氧-氧化铝纳米复合材料的电学和力学性能取决于纳米填料在环氧基体中的均匀分散。使用1wt%、3wt%和5wt%的氧化铝纳米填料制备环氧-氧化铝纳米复合材料,并通过实验和建模研究分析其电学和力学性能。利用荧光纤维技术和超高频(UHF)技术,在交流和直流电压下识别了水滴引发的电晕起始电压(CIV)。随着液滴数量的增加,由水滴形成的CIV急剧减少,荧光纤维技术被发现对识别水滴引发的放电更敏感。提出了一个微观力学模型来分析氧化铝纳米颗粒的界面和团聚性质对环氧-氧化铝纳米复合材料拉伸强度的综合影响。通过采用氧化铝纳米颗粒的非参数分布来分析ξagg、Eagle和E的变化,并且杨氏模量随着氧化铝纳米填料分散水平的增加而增加。聚集颗粒的存在对纳米复合材料的拉伸性能表现出负面影响。
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Influence of Nanofiller Dispersion on Electrical and Mechanical Properties of Epoxy Alumina Nanocomposites
The electrical and mechanical properties of the epoxy alumina nanocomposites depend on the uniform dispersion of the nanofiller in the epoxy matrix. Epoxy alumina nanocomposites were prepared using 1, 3, and 5 wt% of alumina nanofiller, and electrical and mechanical properties were analyzed using experimental and modelling studies. Water droplet initiated corona inception voltage (CIV) was identified using fluorescence fiber technique and by Ultra High Frequency (UHF) technique, under AC and DC voltages. The CIV formed due to water droplet have reduced drastically with increase in number of droplets and fluorescent fiber technique found to be more sensitive to identify water droplet initiated discharges. A micro mechanical model was proposed to analyse the combined effect of the interphase and agglomeration properties of the alumina nanoparticles on the tensile strength of epoxy alumina nanocomposites. Variation in ϕagg, Eagg, and E were analysed by adopting the non-parametric distribution of alumina nanoparticles and Young’s modulus increased with the increment in the alumina nanofiller dispersion level. The presence of aggregated particles exhibits a negative effect on the tensile properties of nanocomposites.
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CiteScore
1.90
自引率
25.00%
发文量
32
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