{"title":"协同相互作用对铁(II)配合物中自旋交叉现象的影响","authors":"M. L. Seredyuk, K. O. Znovjyak, I. O. Fritsky","doi":"10.1007/s11237-022-09725-6","DOIUrl":null,"url":null,"abstract":"<div><div><p>The theoretical principles of a spin transition phenomenon in pseudo-octahedral iron(II) complexes are summarized. The intrinsic transfer of electrons between d-orbitals of a central ion under the action of external factors and the corresponding changes in the structural, spectral, and magnetic characteristics of matter are considered. Cooperative interactions that lead to the appearance of hysteresis of physical properties have been studied in detail. Perspective areas of practical applications of compounds with spin transitions have been provided.</p></div></div>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2022-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of Cooperative Interactions on the Spin Crossover Phenomenon in Iron(II) Complexes: A Review\",\"authors\":\"M. L. Seredyuk, K. O. Znovjyak, I. O. Fritsky\",\"doi\":\"10.1007/s11237-022-09725-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div><p>The theoretical principles of a spin transition phenomenon in pseudo-octahedral iron(II) complexes are summarized. The intrinsic transfer of electrons between d-orbitals of a central ion under the action of external factors and the corresponding changes in the structural, spectral, and magnetic characteristics of matter are considered. Cooperative interactions that lead to the appearance of hysteresis of physical properties have been studied in detail. Perspective areas of practical applications of compounds with spin transitions have been provided.</p></div></div>\",\"PeriodicalId\":796,\"journal\":{\"name\":\"Theoretical and Experimental Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2022-08-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Theoretical and Experimental Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11237-022-09725-6\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical and Experimental Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11237-022-09725-6","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Influence of Cooperative Interactions on the Spin Crossover Phenomenon in Iron(II) Complexes: A Review
The theoretical principles of a spin transition phenomenon in pseudo-octahedral iron(II) complexes are summarized. The intrinsic transfer of electrons between d-orbitals of a central ion under the action of external factors and the corresponding changes in the structural, spectral, and magnetic characteristics of matter are considered. Cooperative interactions that lead to the appearance of hysteresis of physical properties have been studied in detail. Perspective areas of practical applications of compounds with spin transitions have been provided.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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