椰壳基磁性吸附剂在消泡应用中的潜在应用

Felicia Terry Lo , Soh Fong Lim , Sing Ngie David Chua , Kok Keong Lau , Sim Yee Chin
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引用次数: 2

摘要

吸收法是石油天然气工业中最常用的脱硫方法。然而,该过程确实具有几个后果,这些后果将触发泡沫的泡沫形成,从而降低传质效率和吸收能力,以及胺溶液带入下游过程。利用磁性活性炭(MAC)对活性甲基二乙醇胺(MDEA)中不希望有的污染物进行了去除。本工作以椰子壳为原料,通过化学活化和共沉淀的方法合成了MAC。基于活化的MDEA溶剂在不同持续时间和不同量下与MAC接触后的发泡行为来评估该材料作为吸附剂的性能。通过气体扩散器将氮气引入溶剂中以产生泡沫。结果表明,活化MDEA溶剂产生的泡沫体积随着MAC接触时间和接触量的增加而减小。经鉴定,MAC的最高去除效率是在MAC和活化的MDEA溶剂接触1小时时,泡沫破裂时间减少到10–30分钟。同时,在溶剂中加入50%的MAC可以将泡沫破裂时间进一步缩短至5–10分钟。通过各种仪器分析对制备的MAC的特性进行了评估。本研究表明,椰子壳合成的MAC在去除活化MDEA溶剂中的污染物以减少泡沫形成方面具有良好的吸附潜力。
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Potential use of coconut husk-based magnetic sorbent for defoaming application

Absorption process is the most common method that is being applied to sweeten sour gas in the oil and gas industry. However, this process does have several consequences which will trigger the foam formation of foam that will reduce the mass transfer efficiency and absorption capacity as well as amine solutions carryover to the downstream processes. The removal of undesired contaminants in activated methyldiethanolamine (MDEA) was conducted by utilizing magnetic activated carbon (MAC). In this work, MAC was synthesized from coconut husk through chemical activation and co-precipitation methods. The performance of this material as an adsorbent was evaluated based on the foaming behaviour of activated MDEA solvent after being contacted with MAC at different duration and varying amounts. Nitrogen gas was introduced into the solvent through a gas diffuser to create foam. Based on the results, the foam volume generated by activated MDEA solvent was identified to decrease with the increase in both MAC contact time and amount. The highest removal efficiency by MAC was identified to be at 1 h contact time between MAC and activated MDEA solvent where the foam breaking time was reduced to 10–30 min. Meanwhile, the addition of 50 % MAC into the solvent was able to further decrease the foam breaking time to 5–10 min. The characteristics of the prepared MAC were evaluated through various instrumental analyses. This study shows that the MAC synthesized from coconut husk has a good potential as an adsorbent in removing the contaminants in activated MDEA solvent to reduce foam formation.

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