缓凝剂对不同温度下白硅酸盐水泥水化、流变和抗压强度的影响

Rayara Costa , Thiago Cardoso , Maxwell Degen , Laura Silvestro , Erich Rodríguez , Ana Paula Kirchheim
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引用次数: 2

摘要

白水泥的特点是铝酸三钙(C3A)含量高于传统硅酸盐水泥;因此,它可以缩短凝结时间,特别是在炎热的天气条件下,限制材料的使用时间。延迟这些材料凝结时间的一种方法是使用缓凝剂(RA)。然而,关于RA对白水泥流变性能的影响,仍存在知识空白。本研究旨在评估两种RA对两种白水泥的微坍落度、流变参数、水化动力学和抗压强度的影响。此外,25和40的温度的影响⁰C对外加剂的性能也进行了评估。两种RA均具有分散作用,降低了水泥浆体的动态屈服应力和塑性粘度。此外,外加剂将水泥水化的诱导期延长了15.4小时,而不会显著影响25℃下72小时的累积热量⁰C.40⁰C、 两种RA均表现出较低的分散和阻滞作用。尽管RA延缓了WC的初始水化反应,但在水化三天后,它提高了砂浆的力学性能。
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Influence of retarder admixtures on the hydration, rheology, and compressive strength of white Portland cements under different temperatures

White cement is characterized by higher tricalcium aluminate (C3A) contents than conventional Portland cement; thus, it can present a reduced setting time, especially under hot weather conditions, limiting the material's application period. An approach to delay these materials' setting time is using retarder admixtures (RA). Nevertheless, there is a knowledge gap regarding the effect of RA on the rheological properties of white cement. This study aimed to evaluate the effect of two types of RA on the mini-slump, rheological parameters, hydration kinetics, and compressive strength of two white cements. Furthermore, the effect of temperatures of 25 and 40 ⁰C on the performance of the admixtures was also assessed. Both RA showed a dispersing effect, reducing cement pastes' dynamic yield stress and plastic viscosity. Moreover, the admixtures extended the induction period of cement hydration by up to 15.4 h without significantly affecting the 72-h cumulative heat at a temperature of 25 ⁰C. At 40 ⁰C, both RA exhibited a lower dispersing and retarding effect. Although RA delayed the initial hydration reactions of the WC, it enhanced the mechanical performance of the mortars after three days of hydration.

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