硫铝酸盐钙水泥体系固化最佳要求的研究

B. Cansu Acarturk, Lisa E. Burris
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摘要

湿养护通过增加总水化、致密微观结构和降低混凝土渗透性来提高普通硅酸盐水泥(OPC)混凝土的耐久性和强度。通常,建议对OPC进行湿法固化,直到其获得>;设计抗压强度的70%,通常至少持续7天。硫铝酸钙(CSA)水泥由于其与OPC不同的相组成、快速水合和强度增加,可以减少固化时间要求。快速水合还可以防止与OPC固化要求相关的一些缺点,例如固化时间长、与使用高水量相关的成本以及固化过程的监督需求。此外,重要的是要了解目前指定用于CSA系统中OPC的各种固化方案的使用效果。本研究调查了各种养护持续时间和养护溶液成分,以了解它们对CSA水化、强度发展和收缩的影响。结果表明,3天的湿养护有助于获得足够的强度并完成水化反应。此外,即使湿养护CSA样品1天,其收缩率也低于7天养护OPC样品,并可能减少混凝土路面的裂缝。通过在去离子水或硫酸钙饱和溶液中浸泡样品进行固化,与雾固化相比,强度降低了18%或更大。
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Investigations of the optimal requirements for curing of calcium sulfoaluminate cement systems

Wet curing improves ordinary portland cement (OPC) concrete durability and strength by increasing total hydration, densifying microstructure, and decreasing concrete permeability. In general, wet curing is recommended for OPC until it gains >70% of the designed compressive strength, typically for at least 7 days. Calcium sulfoaluminate (CSA) cement may allow for decreased curing time requirements due to its different phase composition from that of OPC, rapid hydration, and strength gain. Rapid hydration may also prevent some disadvantages associated with OPC curing requirements, such as long curing times, costs associated with the use of high-water quantities, and supervision needs for curing processes. In addition, it is important to understand the effect of use of various curing regimes that are currently specified for use with OPC when applied in CSA systems. This study investigated a variety of curing durations and curing solution compositions to understand their effects on CSA hydration, strength development, and shrinkage. The results demonstrate that 3-day moist curing promotes adequate strength gain and completion of hydration reactions. Additionally, wet curing CSA samples even for 1 day led to lower shrinkage than 7-day cured OPC samples and may result in reduced cracking in concrete pavements. Curing through ponding of samples in deionized water or calcium sulfate-saturated solution resulted in strength reductions of 18% or greater relative to fog-curing.

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