β-环糊精对二苯甲酮的影响及其对棉织物UVR过滤的影响

IF 1.7 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Journal of Inclusion Phenomena and Macrocyclic Chemistry Pub Date : 2023-03-27 DOI:10.1007/s10847-023-01184-3
Sivakumar Krishnamoorthy, Nalini Allabasha, Murali Krishnan Mani, Ajoy K. Sarkar
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引用次数: 1

摘要

研究了β-CD对4种二苯甲酮(BP, HBP, d-HBP, t-HBP)的影响及其对府绸棉织物紫外线防护系数(UPF)的影响。bp的UPF值显著提高:β-CD复合物处理过的织物(比未经处理/用游离bp处理过的织物)。通过研究客体(bp:吸收剂)-宿主(β-CD:增强剂)过程,证实了β-CD对羟基取代bp互变异构的影响。-OH取代苯向1°边缘取向和bp在β-CD中间的C = O基团定位可归因于空间效应驱动的客体分子偏好以实现刚性配合。β-CD呈现的刚性配合提高了bp的光稳定性,并通过酮烯醇互变异构有效地消散UVR。具有最高UPF(= 51)的d-HBP:β-CD复合物被确定为生产防晒服的潜在应用材料。
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Effect of β-cyclodextrin on benzophenones and its impact on UVR filtration of cotton fabric through ‘guest absorber—host enhancer’ mechanism

The impact of β-CD on 4 benzophenones (BPs) [namely, BP, HBP, d-HBP, t-HBP] and its resultant effect on the ultraviolet protection factor (UPF) of poplin cotton fabric are tested. Drastic enhancement in the UPF values for BPs:β-CD complexes treated fabrics is noticed (than the untreated/fabric treated with free BPs). The impact of β-CD on the tautomerism of hydroxyl substituted BPs are demonstrated by investigatingthe guest (BPs:absorbers)-host(β-CD:enhancer) process. Orientation of -OH substituted benzene towards 1° rim and positioning of C = O group of BPs in the middle of β-CD could be attributed to the steric effect driven preference of the guest molecules for achieving a rigid fit. Rigid fit rendered by β-CD improves the photostability of BPs and dissipates UVR efficiently through keto-enol tautomerization. With the highest UPF (= 51) d-HBP:β-CD complex is identified as a potential application material for producing sun-protective clothing.

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来源期刊
Journal of Inclusion Phenomena and Macrocyclic Chemistry
Journal of Inclusion Phenomena and Macrocyclic Chemistry Agricultural and Biological Sciences-Food Science
CiteScore
4.10
自引率
8.70%
发文量
54
期刊介绍: The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites. The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.
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