Sivakumar Krishnamoorthy, Nalini Allabasha, Murali Krishnan Mani, Ajoy K. Sarkar
{"title":"β-环糊精对二苯甲酮的影响及其对棉织物UVR过滤的影响","authors":"Sivakumar Krishnamoorthy, Nalini Allabasha, Murali Krishnan Mani, Ajoy K. Sarkar","doi":"10.1007/s10847-023-01184-3","DOIUrl":null,"url":null,"abstract":"<div><p>The impact of β-CD on 4 benzophenones (<i>BPs</i>) [namely, <i>BP</i>, <i>HBP</i>, <i>d-HBP</i>, <i>t-HBP</i>] and its resultant effect on the ultraviolet protection factor (UPF) of poplin cotton fabric are tested. Drastic enhancement in the UPF values for <i>BPs:β-CD</i> complexes treated fabrics is noticed (than the untreated/fabric treated with free <i>BPs</i>). The impact of β-CD on the tautomerism of hydroxyl substituted <i>BPs</i> are demonstrated by investigatingthe <i>guest</i> (BPs:absorbers)-<i>host(</i>β-CD:enhancer) process. Orientation of -OH substituted benzene towards 1<sup>°</sup> rim and positioning of C = O group of <i>BPs</i> in the middle of β-CD could be attributed to the steric effect driven preference of the guest molecules for achieving a rigid fit. Rigid fit rendered by <i>β-CD</i> improves the photostability of <i>BPs</i> and dissipates UVR efficiently through <i>keto-enol</i> tautomerization. With the highest UPF (= 51) <i>d-HBP:β-CD complex</i> is identified as a potential application material for producing sun-protective clothing.</p></div>","PeriodicalId":54324,"journal":{"name":"Journal of Inclusion Phenomena and Macrocyclic Chemistry","volume":"103 3-4","pages":"131 - 145"},"PeriodicalIF":1.7000,"publicationDate":"2023-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Effect of β-cyclodextrin on benzophenones and its impact on UVR filtration of cotton fabric through ‘guest absorber—host enhancer’ mechanism\",\"authors\":\"Sivakumar Krishnamoorthy, Nalini Allabasha, Murali Krishnan Mani, Ajoy K. Sarkar\",\"doi\":\"10.1007/s10847-023-01184-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The impact of β-CD on 4 benzophenones (<i>BPs</i>) [namely, <i>BP</i>, <i>HBP</i>, <i>d-HBP</i>, <i>t-HBP</i>] and its resultant effect on the ultraviolet protection factor (UPF) of poplin cotton fabric are tested. Drastic enhancement in the UPF values for <i>BPs:β-CD</i> complexes treated fabrics is noticed (than the untreated/fabric treated with free <i>BPs</i>). The impact of β-CD on the tautomerism of hydroxyl substituted <i>BPs</i> are demonstrated by investigatingthe <i>guest</i> (BPs:absorbers)-<i>host(</i>β-CD:enhancer) process. Orientation of -OH substituted benzene towards 1<sup>°</sup> rim and positioning of C = O group of <i>BPs</i> in the middle of β-CD could be attributed to the steric effect driven preference of the guest molecules for achieving a rigid fit. Rigid fit rendered by <i>β-CD</i> improves the photostability of <i>BPs</i> and dissipates UVR efficiently through <i>keto-enol</i> tautomerization. With the highest UPF (= 51) <i>d-HBP:β-CD complex</i> is identified as a potential application material for producing sun-protective clothing.</p></div>\",\"PeriodicalId\":54324,\"journal\":{\"name\":\"Journal of Inclusion Phenomena and Macrocyclic Chemistry\",\"volume\":\"103 3-4\",\"pages\":\"131 - 145\"},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2023-03-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Inclusion Phenomena and Macrocyclic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10847-023-01184-3\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inclusion Phenomena and Macrocyclic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10847-023-01184-3","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Effect of β-cyclodextrin on benzophenones and its impact on UVR filtration of cotton fabric through ‘guest absorber—host enhancer’ mechanism
The impact of β-CD on 4 benzophenones (BPs) [namely, BP, HBP, d-HBP, t-HBP] and its resultant effect on the ultraviolet protection factor (UPF) of poplin cotton fabric are tested. Drastic enhancement in the UPF values for BPs:β-CD complexes treated fabrics is noticed (than the untreated/fabric treated with free BPs). The impact of β-CD on the tautomerism of hydroxyl substituted BPs are demonstrated by investigatingthe guest (BPs:absorbers)-host(β-CD:enhancer) process. Orientation of -OH substituted benzene towards 1° rim and positioning of C = O group of BPs in the middle of β-CD could be attributed to the steric effect driven preference of the guest molecules for achieving a rigid fit. Rigid fit rendered by β-CD improves the photostability of BPs and dissipates UVR efficiently through keto-enol tautomerization. With the highest UPF (= 51) d-HBP:β-CD complex is identified as a potential application material for producing sun-protective clothing.
期刊介绍：
The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites.
The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.
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