熔融纺丝CoMnSi(B)合金的磁性能

IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Journal of Superconductivity and Novel Magnetism Pub Date : 2023-06-30 DOI:10.1007/s10948-023-06597-2
Rafael G. Suarez, Aida Miranda, J. L. Sánchez-Llamazares, I. Betancourt
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引用次数: 0

摘要

采用熔融纺丝技术制备了MnCoSi和MnCoSiB0.5合金,获得了平均晶粒尺寸小于10微米的多晶组织。x射线相分布分析表明,材料具有正交结构和tini型晶体对称。通过扫描电镜验证了化学均匀性,而磁性行为符合矫顽力值低于20 Oe,饱和磁化强度为80 μ emu/g的软磁材料。这些MnCoSiB合金的磁热响应的最大磁熵变化为1.0?J/kg K(磁场变化为2.0特斯拉)和吸引制冷剂容量超过100?J/kg,与等效的MnCoGe合金相比有显著的提高。
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Magnetic Properties of Melt-Spun CoMnSi(B) Alloys

MnCoSi and MnCoSiB0.5 alloys were obtained by melt-spinning technique in order to attain polycrystalline microstructures with average grain sizes well below 10 microns. Phase distribution studied by X-ray analysis indicated single-phase materials with orthorhombic structure and TiNiSi-type crystal symmetry. Chemical homogeneity was verified by means of scanning electron microscopy, whereas magnetic behavior corresponded to soft magnetic materials with coercivity values lower than 20 Oe and saturation magnetization of 80?emu/g. Magnetocaloric response of these MnCoSiB alloys was characterized by a maximum magnetic entropy change of 1.0?J/kg K (for a magnetic field variation of 2.0 Tesla) and attractive refrigerant capacity over 100?J/kg, which represents a significant enhancement respect to equivalent MnCoGe alloys.

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来源期刊
Journal of Superconductivity and Novel Magnetism
Journal of Superconductivity and Novel Magnetism 物理-物理:凝聚态物理
CiteScore
3.70
自引率
11.10%
发文量
342
审稿时长
3.5 months
期刊介绍: The Journal of Superconductivity and Novel Magnetism serves as the international forum for the most current research and ideas in these fields. This highly acclaimed journal publishes peer-reviewed original papers, conference proceedings and invited review articles that examine all aspects of the science and technology of superconductivity, including new materials, new mechanisms, basic and technological properties, new phenomena, and small- and large-scale applications. Novel magnetism, which is expanding rapidly, is also featured in the journal. The journal focuses on such areas as spintronics, magnetic semiconductors, properties of magnetic multilayers, magnetoresistive materials and structures, magnetic oxides, etc. Novel superconducting and magnetic materials are complex compounds, and the journal publishes articles related to all aspects their study, such as sample preparation, spectroscopy and transport properties as well as various applications.
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