易北河河口上游再悬浮沉积物的耗氧量:过程识别与预测

IF 1.7 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Aquatic Geochemistry Pub Date : 2021-11-30 DOI:10.1007/s10498-021-09401-6
M. Spieckermann, A. Gröngröft, M. Karrasch, A. Neumann, A. Eschenbach
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引用次数: 6

摘要

沉积物的再悬浮导致营养物质和有机物质释放到上覆水柱的增加,这可能对氧收支产生负面影响。特别是在氧饱和度较低、生物活性较高的温暖月份,易北河河口等河口的氧含量可达到临界阈值。许多研究已经处理了在再悬浮事件中发生的营养通量。然而,影响耗氧势(OCP)和不同生化过程的沉积物性质尚未得到详细研究。为了填补这一空白,我们研究了易北河河口上游21个地点沉积物的生物地球化学组成、质地和OCP,以及一个地点2年的时间变化(每月采样)。在7天的再悬浮过程中,沉积物的OCP可以用硫酸盐形成、硝化和矿化过程来描述。叶绿素、总氮(Ntotal)和总有机碳与OCP的相关性最高。在此基础上,建立了以单一泥沙参数(Ntotal)计算易北河上游入海口OCP的预测模型。该模型非常适合计算汉堡港区在相关温暖月份的重悬浮沉积物耗氧量,其标准化均方根误差为< 0.11±0.13。由此可以计算出注水疏浚、船致波等维护措施对水体氧收支的影响。
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Oxygen Consumption of Resuspended Sediments of the Upper Elbe Estuary: Process Identification and Prognosis

The resuspension of sediment leads to an increased release of nutrients and organic substances into the overlying water column, which can have a negative effect on the oxygen budget. Especially in the warmer months with a lower oxygen saturation and higher biological activity, the oxygen content can reach critical thresholds in estuaries like the upper Elbe estuary. Many studies have dealt with the nutrient fluxes that occur during a resuspension event. However, the sediment properties that influence the oxygen consumption potential (OCP) and the different biochemical processes have not been examined in detail. To fill this gap, we investigated the biogeochemical composition, texture, and OCP of sediments at 21 locations as well as the temporal variability within one location for a period of 2 years (monthly sampling) in the upper Elbe estuary. The OCP of sediments during a seven-day resuspension event can be described by the processes of sulphate formation, nitrification, and mineralisation. Chlorophyll, total nitrogen (Ntotal), and total organic carbon showed the highest correlations with the OCP. Based on these correlations, we developed a prognosis model to calculate the OCP for the upper Elbe estuary with a single sediment parameter (Ntotal). The model is well suited to calculate the oxygen consumption of resuspended sediments in the Hamburg port area during the relevant warmer months and shows a normalised root mean squared error of < 0.11 ± 0.13. Thus, the effect of maintenance measures such as water injection dredging and ship-induced wave on the oxygen budget of the water can be calculated.

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来源期刊
Aquatic Geochemistry
Aquatic Geochemistry 地学-地球化学与地球物理
CiteScore
4.30
自引率
0.00%
发文量
6
审稿时长
1 months
期刊介绍: We publish original studies relating to the geochemistry of natural waters and their interactions with rocks and minerals under near Earth-surface conditions. Coverage includes theoretical, experimental, and modeling papers dealing with this subject area, as well as papers presenting observations of natural systems that stress major processes. The journal also presents `letter''-type papers for rapid publication and a limited number of review-type papers on topics of particularly broad interest or current major controversy.
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