{"title":"水溶液电渗析中硝酸盐和醋酸离子的过电选择性预测","authors":"P.R. Shah, A.S. Kovvali, G.Y. Khan, A.A. Khan","doi":"10.1016/0300-9467(93)80002-6","DOIUrl":null,"url":null,"abstract":"<div><p>Electrodialysis of aqueous solutions of acetic and nitric acids encountered in the industrial practice of deacidification of raw glyoxal solutions has been carried out to investigate the permselectivity of the system. The dependence of the permselectivity coefficient τ on experimental parameters such as flow velocity (<em>V</em>), current density (<em>I</em>), concentration of anions (<em>C</em><sub><em>i</em></sub>), etc. has been evaluated. A correlation between τ and the critical parameters has been obtained. Well-known theoretical equations have been used to calculate τ at limiting current density <em>I</em><sub>lim</sub> and as <em>I</em> approaches zero. Calculated results are compared with observed values. Limitations of theoretical procedures when applied to a system containing a weak acid are explained.</p></div>","PeriodicalId":101225,"journal":{"name":"The Chemical Engineering Journal","volume":"51 1","pages":"Pages 1-6"},"PeriodicalIF":0.0000,"publicationDate":"1993-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0300-9467(93)80002-6","citationCount":"0","resultStr":"{\"title\":\"Prediction of permselectivity of nitrate and acetate ions in the electrodialysis of aqueous solutions\",\"authors\":\"P.R. Shah, A.S. Kovvali, G.Y. Khan, A.A. Khan\",\"doi\":\"10.1016/0300-9467(93)80002-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Electrodialysis of aqueous solutions of acetic and nitric acids encountered in the industrial practice of deacidification of raw glyoxal solutions has been carried out to investigate the permselectivity of the system. The dependence of the permselectivity coefficient τ on experimental parameters such as flow velocity (<em>V</em>), current density (<em>I</em>), concentration of anions (<em>C</em><sub><em>i</em></sub>), etc. has been evaluated. A correlation between τ and the critical parameters has been obtained. Well-known theoretical equations have been used to calculate τ at limiting current density <em>I</em><sub>lim</sub> and as <em>I</em> approaches zero. Calculated results are compared with observed values. Limitations of theoretical procedures when applied to a system containing a weak acid are explained.</p></div>\",\"PeriodicalId\":101225,\"journal\":{\"name\":\"The Chemical Engineering Journal\",\"volume\":\"51 1\",\"pages\":\"Pages 1-6\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1993-02-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0300-9467(93)80002-6\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The Chemical Engineering Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0300946793800026\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Chemical Engineering Journal","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0300946793800026","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Prediction of permselectivity of nitrate and acetate ions in the electrodialysis of aqueous solutions
Electrodialysis of aqueous solutions of acetic and nitric acids encountered in the industrial practice of deacidification of raw glyoxal solutions has been carried out to investigate the permselectivity of the system. The dependence of the permselectivity coefficient τ on experimental parameters such as flow velocity (V), current density (I), concentration of anions (Ci), etc. has been evaluated. A correlation between τ and the critical parameters has been obtained. Well-known theoretical equations have been used to calculate τ at limiting current density Ilim and as I approaches zero. Calculated results are compared with observed values. Limitations of theoretical procedures when applied to a system containing a weak acid are explained.
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