NR胶乳辐射硫化中试研究

M. Ridwan
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引用次数: 3

摘要

辐照乳胶作为商业用途原料的潜力正在印度尼西亚的中试工厂规模上进行测试,该工厂拥有225千瓦的Co-60辐照设施,每年可辐照1000吨离心乳胶。该设施由印度尼西亚BATAN和日本JAERI联合设计,并由开发计划署/原子能机构、日本政府和印度尼西亚政府根据开发计划署/原子能机构同位素和辐射技术工业应用区域合作协定项目联合资助。该设施为水池式,可容纳400 kCi Co-60。Co-60机架有两种形状,板式和圆柱形。板形光源用于天然胶乳照射,圆柱形光源用于其他照射服务。硫化系统由乳化装置(高度650 mm,直径500 mm)、混合装置(高度1900mm,直径1200 mm)和硫化反应器(高度1800 mm,直径1300 mm)三大部分组成。前两个组件位于屏蔽室外,第三个组件位于辐照室内。与传统的热工工艺相比,辐射硫化工艺是一种更简单的节能工艺,传统的热工工艺有浸前和浸后两个硫化步骤。辐照后的NR胶乳的物理力学性能与硫硫化胶乳相当,并受辐照剂量、增感剂含量、干胶含量和贮存时间等诸多因素的影响。
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Pilot scale experiments on radiation vulcanization of NR latex

The potential of irradiated latex as raw material of commercial use is under testing on pilot plant scale in Indonesia which has 225 kCi Co-60 irradiation facility and can irradiate 1000 tonnes of centrifuged latex per annum. The facility was jointly designed by BATAN of Indonesia and JAERI of Japan and was jointly financed by UNDP/IAEA, Government of Japan and Government of Indonesia under UNDP/IAEA Regional Cooperative Agreement Project on Industrial Application of Isotopes and Radiation Technology. The facility is a water pool type and can accomodate 400 kCi Co-60. The Co-60 rack has two shapes, plate and cylindrical shapes. The plate shape source is used for natural rubber latex irradiation and the cylindrical one is used for other irradiation services. The vulcanization system consists of three major components : emulsification unit ( height : 650 mm, diameter 500 mm ), mixing unit ( height : 1900mm, diameter 1200 mm ) and vulcanization reactor ( height : 1800 mm, diameter 1300 mm ). The first two components are located outside shielded room while the third one-in irradiation room. The radiation vulcanization process is a much simpler energy saving process comparedto the conventional thermal process which has two vulcanization steps before and after dipping.

The physical and mechanical properties of irradiated NR Latex are comparable to those of sulfur vulcanized, and depend on many factors such as irradiation dose, sensitizer content, dry rubber content and storage time.

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