联萘桥接席夫碱的合成与结构

IF 3.1 4区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Research in Chinese Universities Pub Date : 2008-09-01 DOI:10.1016/S1005-9040(08)60118-X

Bin WANG, Min-xiong LI, Shan-sheng XU, Hai-bin SONG, Bai-quan WANG

引用次数: 0

摘要

二萘呋喃与锂在无水乙醚中反应得到相应的C, o -二甲基化中间体，经DMF在- 78℃处理后，水解得到2′-羟基-1,1′-二萘-2-乙醛，产率高。然后通过2′-羟基-1,1′-联萘-2-乙醛与相应的芳香胺缩合制备了联萘桥接席夫碱。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Syntheses and Structures of Binaphthyl-bridged Schiff Bases

The reaction of dinaphthofuran with lithium in anhydrous diethyl ether led to a solution of the corresponding C,O-dilithiated intermediate which, upon treatment with DMF at −78°C, afforded, after hydrolysis, 2′-hydroxy-1,1′-binaphthyl-2-carbaldehyde in a good yield. Then binaphthyl-bridged Schiff bases were prepared by the condensation of 2′-hydroxy-1,1′-binaphthyl-2-carbaldehyde with the corresponding aromatic amines.

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来源期刊

Chemical Research in Chinese Universities 化学-化学综合

CiteScore

5.30

自引率

6.50%

发文量

152

审稿时长

3.0 months

期刊介绍： The journal publishes research articles, letters/communications and reviews written by faculty members, researchers and postgraduates in universities, colleges and research institutes all over China and overseas. It reports the latest and most creative results of important fundamental research in all aspects of chemistry and of developments with significant consequences across subdisciplines. Main research areas include (but are not limited to): Organic chemistry (synthesis, characterization, and application); Inorganic chemistry (bio-inorganic chemistry, inorganic material chemistry); Analytical chemistry (especially chemometrics and the application of instrumental analysis and spectroscopy); Physical chemistry (mechanisms, catalysis, thermodynamics and dynamics); Polymer chemistry and polymer physics (mechanisms, material, catalysis, thermodynamics and dynamics); Quantum chemistry (quantum mechanical theory, quantum partition function, quantum statistical mechanics); Biochemistry; Biochemical engineering; Medicinal chemistry; Nanoscience (nanochemistry, nanomaterials).