{"title":"钠-铯合金体系固-液相平衡","authors":"J. Ott, J. Goates, D. E. Oyler","doi":"10.1039/TF9716700031","DOIUrl":null,"url":null,"abstract":"Thermal methods were used to determine with high precision the solid-liquid phase equilibria diagram for the sodium-caesium system. The results differ greatly from those of earlier workers, especially near the eutectic composition, where differences in melting points as large as 35 K occur. Identification of the phases involved in the peritectic halt was not conclusive, but does support the proposal that the peritectic results from the formation of an Na2Cs intermetallic compound by a sluggish reaction.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"67 1","pages":"31-34"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716700031","citationCount":"10","resultStr":"{\"title\":\"Solid-liquid phase equilibrium in the sodium-caesium alloy system\",\"authors\":\"J. Ott, J. Goates, D. E. Oyler\",\"doi\":\"10.1039/TF9716700031\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Thermal methods were used to determine with high precision the solid-liquid phase equilibria diagram for the sodium-caesium system. The results differ greatly from those of earlier workers, especially near the eutectic composition, where differences in melting points as large as 35 K occur. Identification of the phases involved in the peritectic halt was not conclusive, but does support the proposal that the peritectic results from the formation of an Na2Cs intermetallic compound by a sluggish reaction.\",\"PeriodicalId\":23290,\"journal\":{\"name\":\"Transactions of The Faraday Society\",\"volume\":\"67 1\",\"pages\":\"31-34\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1039/TF9716700031\",\"citationCount\":\"10\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transactions of The Faraday Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/TF9716700031\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716700031","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Solid-liquid phase equilibrium in the sodium-caesium alloy system
Thermal methods were used to determine with high precision the solid-liquid phase equilibria diagram for the sodium-caesium system. The results differ greatly from those of earlier workers, especially near the eutectic composition, where differences in melting points as large as 35 K occur. Identification of the phases involved in the peritectic halt was not conclusive, but does support the proposal that the peritectic results from the formation of an Na2Cs intermetallic compound by a sluggish reaction.