钠-铯合金体系固-液相平衡

J. Ott, J. Goates, D. E. Oyler
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引用次数: 10

摘要

采用热法对钠-铯体系的固液平衡图进行了高精度的测定。结果与早期工人的结果大不相同,特别是在共晶成分附近,熔点差异高达35 K。对包晶中所涉及的相的鉴定并不是决定性的,但确实支持了包晶是由缓慢反应形成的Na2Cs金属间化合物的提议。
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Solid-liquid phase equilibrium in the sodium-caesium alloy system
Thermal methods were used to determine with high precision the solid-liquid phase equilibria diagram for the sodium-caesium system. The results differ greatly from those of earlier workers, especially near the eutectic composition, where differences in melting points as large as 35 K occur. Identification of the phases involved in the peritectic halt was not conclusive, but does support the proposal that the peritectic results from the formation of an Na2Cs intermetallic compound by a sluggish reaction.
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