表面原子的复合。12个部分。-某些金属和合金表面的氮原子

M. L. Rahman, J. Linnett
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引用次数: 12

摘要

用史密斯侧臂法测量了几种金属和合金表面氮原子的复合系数。钯、银和50/50合金的活性常数表明d带空位不重要。Fe、Ni、Cu和Ni/Cu合金的实验结果表明,这些材料在表面形成硝酸盐,其性质对控制活性起重要作用。
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Recombination of atoms at surfaces. Part 12.—Nitrogen atoms at some metal and alloy surfaces
The recombination coefficients for the recombination of nitrogen atoms on the surface of a number of metals and alloys have been measured using Smith's side-arm method. The constancy of activity for palladium, silver and a 50/50 alloys shows that d-band vacancies are unimportant. The results for Fe, Ni, Cu and Ni/Cu alloys suggest that with these materials a surface nitrate is formed and its properties are important in controlling the activity.
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