{"title":"电解质的表观摩尔体积。第4部分——25°C下甲酰胺中的KCl","authors":"L. Dunn","doi":"10.1039/TF9716702525","DOIUrl":null,"url":null,"abstract":"Apparent molar volumes of KCl in formamide in the concentration range 0.005–1.0 M at 25°C have been measured using a magnetically-operated dilatometer. The Debye-Huckel appa rent molar volume limiting slope for 1-1 electrolytes in formamide at 25°C has been calculated to be 1.104 ml mol– l.½ This value is satisfactorily approached experimentally with KCl in very dilute formamide solutions.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"67 1","pages":"2525-2527"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716702525","citationCount":"6","resultStr":"{\"title\":\"Apparent molar volumes of electrolytes. Part 4.—KCl in formamide at 25°C\",\"authors\":\"L. Dunn\",\"doi\":\"10.1039/TF9716702525\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Apparent molar volumes of KCl in formamide in the concentration range 0.005–1.0 M at 25°C have been measured using a magnetically-operated dilatometer. The Debye-Huckel appa rent molar volume limiting slope for 1-1 electrolytes in formamide at 25°C has been calculated to be 1.104 ml mol– l.½ This value is satisfactorily approached experimentally with KCl in very dilute formamide solutions.\",\"PeriodicalId\":23290,\"journal\":{\"name\":\"Transactions of The Faraday Society\",\"volume\":\"67 1\",\"pages\":\"2525-2527\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1039/TF9716702525\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transactions of The Faraday Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/TF9716702525\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716702525","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 6
摘要
在25℃下，用磁操作膨胀计测量了浓度范围为0.005-1.0 M的甲酰胺中KCl的表观摩尔体积。在25°C时甲酰胺中1-1电解质的Debye-Huckel表观摩尔体积极限斜率计算为1.104 ml mol -1。这个值在实验中用KCl在非常稀的甲酰胺溶液中令人满意地接近。
Apparent molar volumes of electrolytes. Part 4.—KCl in formamide at 25°C
Apparent molar volumes of KCl in formamide in the concentration range 0.005–1.0 M at 25°C have been measured using a magnetically-operated dilatometer. The Debye-Huckel appa rent molar volume limiting slope for 1-1 electrolytes in formamide at 25°C has been calculated to be 1.104 ml mol– l.½ This value is satisfactorily approached experimentally with KCl in very dilute formamide solutions.
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