汞(3p0)反应的相移研究。第3部分。Hg(3p0)与某些伯胺的配合物

C. G. Freeman, M. McEwan, R. Claridge, L. F. Phillips
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引用次数: 6

摘要

测定了乙胺、正丙胺、异丙胺、正丁胺、仲丁胺、异丁胺和叔丁胺与Hg(3P0)的双分子和三分子反应速率常数、与Hg(3P0)配合物的寿命以及与Hg(3P0)配合物的解离能下限。这些结果,当与先前汞敏化发光的量子效率值相补充时,使我们能够评估汞(3P0)在胺敏化分解中的相对重要性。
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Phase-shift studies of Hg(3 P 0) reactions. Part 3.?Complexes of Hg(3 P 0) with some primary amines
Rate constants for bimolecular and termolecular reactions with Hg(3P0), lifetimes of complexes with Hg(3P0), and lower limits for dissociation energies of complexes with Hg(3P0), have been determined for ethylamine, n-propylamine, isopropylamine, n-butylamine, sec-butylamine, isobutylamine and tert-butylamine. These results, when supplemented by previous values for the quantum efficiencies of mercury-sensitized luminescence, allow us to assess the relative importance of Hg(3P0) in the sensitized decompositions of amines.
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