用旋转圆盘法测定石膏多晶样品和硫酸钙正交形式的溶解速率

A. Barton, N. M. Wilde
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引用次数: 64

摘要

用多晶材料旋转圆盘研究了硬石膏和石膏在25℃下的溶解动力学,并用钙选择电极进行了动力学研究。石膏的溶解速率受输运控制,硬石膏的溶解速率介于化学和输运控制之间。
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Dissolution rates of polycrystalline samples of gypsum and orthorhombic forms of calcium sulphate by a rotating disc method
The dissolution into water of anhydrite and gypsum was studied at 25°C using a rotating disc of polycrystalline material, and the kinetics were followed with a calcium selective electrode. The dissolution rate of gypsum was transport controlled while that of anhydrite was intermediate between chemical and transport control.
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