{"title":"一些唑基与铂(II)-甘氨酸的相互作用——动力学、机理和产物表征","authors":"Sukalpa Dey, P. Banerjee","doi":"10.1080/1028662021000062581","DOIUrl":null,"url":null,"abstract":"The kinetics of the reaction of [Pt(digly)(H 2 O)] (where H 2 digly=glycylglycine) with imidazole, pyrazole and triazole were studied at 25°C in aqueous medium by UV-Vis. spectroscopy at I =0.1 mol dm m 3 in the range of pH=5.05-9.00. The entry of the azole bases by the substitution of aqua ligand was revealed. All the products have been characterized through CHN analysis, IR and 1 H NMR spectra. The pH variation data were fitted by a computer fit program and the reactivity of the different azole base species towards the Pt(II) substrate ascertained.","PeriodicalId":54977,"journal":{"name":"Inorganic Reaction Mechanisms","volume":"4 1","pages":"159-167"},"PeriodicalIF":0.0000,"publicationDate":"2002-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Interaction of Some Azole Bases with Platinum(II)-Glycylglycine--Kinetics, Mechanism and Product Characterization\",\"authors\":\"Sukalpa Dey, P. Banerjee\",\"doi\":\"10.1080/1028662021000062581\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The kinetics of the reaction of [Pt(digly)(H 2 O)] (where H 2 digly=glycylglycine) with imidazole, pyrazole and triazole were studied at 25°C in aqueous medium by UV-Vis. spectroscopy at I =0.1 mol dm m 3 in the range of pH=5.05-9.00. The entry of the azole bases by the substitution of aqua ligand was revealed. All the products have been characterized through CHN analysis, IR and 1 H NMR spectra. The pH variation data were fitted by a computer fit program and the reactivity of the different azole base species towards the Pt(II) substrate ascertained.\",\"PeriodicalId\":54977,\"journal\":{\"name\":\"Inorganic Reaction Mechanisms\",\"volume\":\"4 1\",\"pages\":\"159-167\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2002-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Reaction Mechanisms\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/1028662021000062581\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Reaction Mechanisms","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/1028662021000062581","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Interaction of Some Azole Bases with Platinum(II)-Glycylglycine--Kinetics, Mechanism and Product Characterization
The kinetics of the reaction of [Pt(digly)(H 2 O)] (where H 2 digly=glycylglycine) with imidazole, pyrazole and triazole were studied at 25°C in aqueous medium by UV-Vis. spectroscopy at I =0.1 mol dm m 3 in the range of pH=5.05-9.00. The entry of the azole bases by the substitution of aqua ligand was revealed. All the products have been characterized through CHN analysis, IR and 1 H NMR spectra. The pH variation data were fitted by a computer fit program and the reactivity of the different azole base species towards the Pt(II) substrate ascertained.
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