通过测量溶液的蒸气压来测定溶液的渗透压

Randal Thomas Mowbray Rawdon Berkeley, E. Hartley
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引用次数: 2

摘要

1903年5月,我们在一篇初步论文中描述了一些实验,通过这些实验,我们直接测量了蔗糖在水中的强溶液的渗透压。从那时起,用改进的仪器重复了实验,我们希望很快就能公布结果。由于这些结果与理论气体定律相差甚远,因此认为用独立的方法求得相同溶液的渗透压是可取的;对溶液的蒸气压和渗透压的“降低”之间众所周知的联系进行实验研究似乎是合适的。
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The determination of the osmotic pressures of solutions by the measurement of their vapour pressures
In May, 1903, we described, in a preliminary paper, some experiments by which we had measured directly the osmotic pressures of strong solutions of cane sugar in water. Since then a repetition of the experiments with an improved apparatus has been carried out, the results of which we hope to publish very shortly. As these results depart widely from the theoretical gas laws, it was deemed advisable to obtain the osmotic pressures of the same solutions by an independent method; and an experimental investigation of the well known connection between the “lowering” of the vapour pressure of a solution and its osmotic pressure seemed suitable.
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