Mg2存在下质子交换膜的性能

Guo Li, Jinzhu Tan, J. Gong, Xiaowei Zhang, Yanchao Xin, Xuejia Hu
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引用次数: 8

摘要

质子交换膜(PEM)燃料电池被认为是一种潜在的可再生能源,它可能为减少二氧化碳排放、减少对化石燃料的依赖和提高能源效率提供一种可能的长期解决方案。尽管已经取得了很大的进步,但长期的稳定性和耐久性仍然是一个问题。污染离子对PEM燃料电池的电性能有重要影响。本文以Mg2+浓度为函数,研究了Mg2+污染对PEM燃料电池性能的影响。选择两个浓度水平的Mg2+。从实验结果可以看出,在阳极燃料流中注入Mg2+后,燃料电池的性能明显下降。随着Mg2+浓度的增加,燃料电池的电压和功率密度随时间的推移下降越来越大。在燃料电池中,Mg2+主要造成了从阳极催化剂到膜的浓度极化损失。
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Performance of Proton Exchange Membrane in the Presence of Mg2
Proton exchange membrane (PEM) fuel cell is regarded as one of the potential renewable energy which may provide a possible long-term solution to reduce carbon dioxide emissions, reduce fossil fuel dependency and increase energy efficiency. Even though great progress has been made, long-term stability and durability is still an issue. The contamination ion plays an important role on the electrical performance of PEM fuel cell. This paper investigates the effect of Mg2+ contamination on PEM fuel cell performance as a function of Mg2+ concentration. Two levels of Mg2+ concentration was chose. From the experimental results, it can be obtained that a significant drop in fuel cell performance occurred when Mg2+ was injected into the anode fuel stream. The voltage and power density of fuel cell decreased larger and larger with increase of Mg2+ concentration over time. The Mg2+ mainly caused the concentration polarization loss from the anode catalyst to the membrane in fuel cell.
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期刊介绍: The Journal of Fuel Cell Science and Technology publishes peer-reviewed archival scholarly articles, Research Papers, Technical Briefs, and feature articles on all aspects of the science, engineering, and manufacturing of fuel cells of all types. Specific areas of importance include, but are not limited to: development of constituent materials, joining, bonding, connecting, interface/interphase regions, and seals, cell design, processing and manufacturing, multi-scale modeling, combined and coupled behavior, aging, durability and damage tolerance, reliability, availability, stack design, processing and manufacturing, system design and manufacturing, power electronics, optimization and control, fuel cell applications, and fuels and infrastructure.
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