在HCl介质中对低碳钢的抑绿作用

R. Rajalakshmi, A. Safina
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引用次数: 8

摘要

腐蚀控制方法,特别是抑制剂的使用,在消除腐蚀的当前情况下已经变得非常重要,对生态友好的追求仍在继续。为了获得一种廉价、无毒、环保的抑制剂配方,本文采用经典失重法和电化学极化法研究了椰子树雄蕊花提取物的使用。在1M HCl中,酸浸提液对低碳钢的缓蚀效果可达97.3%。通过温度研究计算了腐蚀过程的热力学参数。雄蕊花提取物在酸性溶液中的吸附行为可以用Langmuir等温线和Temkin等温线近似。用塔菲尔法、线性极化电阻法和阻抗谱法得到的结果与经典的失重测量结果相关联。Tafel常数ba和bc值证实了雄蕊花提取物具有混合型抑制剂的作用。在抑制剂存在的情况下对金属表面的检查证实了抑制剂在金属表面的沉积。在HCl介质中,Staminate Flower提取物能有效抑制腐蚀,是一种零成本、环保、无毒、经济的缓蚀剂。
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Staminate Flower of Cocos Nucifera as Green Inhibitor for Mild Steel in HCl Medium
Corrosion control methods, especially the use of inhibitors, have gained monumental importance in the present scenario of expunging corrosion and the quest for eco-friendly reasons continues. To arrive at an inexpensive non-toxic, eco-friendly inhibitor formulations the present study on the use of Staminate Flower extract of Cocos Nucifera has been carried out by the classical weight loss measurements and electrochemical polarization measurements. The acid extract could bring out a maximum of 97.3% inhibition of mild steel corrosion in 1M HCl. Thermodynamic parameters of the corrosion process were calculated from temperature study. The adsorptive behaviour of Staminate Flower extract in acid solution may be approximated both by Langmuir and Temkin type isotherms. The results obtained by Tafel, Linear polarization resistance, and impedance spectroscopy have been correlated with the classical weight loss measurements. Values of Tafel constant ba and bc confirmed that the Staminate Flower extract acts like mixed type inhibitor. Examination of the surface of the metal in the presence of the inhibitor confirmed the deposition of inhibitor on the metal surface. The Staminate Flower extract in HCl medium efficiently inhibits the corrosion and proved to be zero cost inhibitor, eco-friendly, non-toxic, and highly economical.
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来源期刊
E-journal of Chemistry
E-journal of Chemistry CHEMISTRY, MULTIDISCIPLINARY-
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