{"title":"聚甲基丙烯酸甲酯凝胶电解质膜的结构与电化学分析","authors":"C. M. Mathew, K. Kesavan, S. Rajendran","doi":"10.1155/2015/494308","DOIUrl":null,"url":null,"abstract":"New gel polymer electrolytes containing poly(vinylidene chloride-co-acrylonitrile) and poly(methyl methacrylate) are prepared by solution casting method. With the addition of 60 wt.% of EC to PVdC-AN/PMMA blend, ionic conductivity value S cm−1 has been achieved. XRD and FT-IR studies have been conducted to investigate the structure and complexation in the polymer gel electrolytes. The FT-IR spectra show that the functional groups C=O and C≡N play major role in ion conduction. Thermal stability of the prepared membranes is found to be about 180°C.","PeriodicalId":13933,"journal":{"name":"International journal of electrochemistry","volume":"2015 1","pages":"1-7"},"PeriodicalIF":2.0000,"publicationDate":"2015-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2015/494308","citationCount":"29","resultStr":"{\"title\":\"Structural and Electrochemical Analysis of PMMA Based Gel Electrolyte Membranes\",\"authors\":\"C. M. Mathew, K. Kesavan, S. Rajendran\",\"doi\":\"10.1155/2015/494308\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"New gel polymer electrolytes containing poly(vinylidene chloride-co-acrylonitrile) and poly(methyl methacrylate) are prepared by solution casting method. With the addition of 60 wt.% of EC to PVdC-AN/PMMA blend, ionic conductivity value S cm−1 has been achieved. XRD and FT-IR studies have been conducted to investigate the structure and complexation in the polymer gel electrolytes. The FT-IR spectra show that the functional groups C=O and C≡N play major role in ion conduction. Thermal stability of the prepared membranes is found to be about 180°C.\",\"PeriodicalId\":13933,\"journal\":{\"name\":\"International journal of electrochemistry\",\"volume\":\"2015 1\",\"pages\":\"1-7\"},\"PeriodicalIF\":2.0000,\"publicationDate\":\"2015-01-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1155/2015/494308\",\"citationCount\":\"29\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International journal of electrochemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1155/2015/494308\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International journal of electrochemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2015/494308","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 29
摘要
采用溶液浇铸法制备了含聚偏氯乙烯-共丙烯腈和聚甲基丙烯酸甲酯的新型凝胶聚合物电解质。加上60磅。%的EC与pvc - an /PMMA共混物的离子电导率达到了S cm−1。用XRD和FT-IR研究了聚合物凝胶电解质的结构和络合作用。FT-IR光谱表明，官能团C=O和C≡N在离子传导中起主要作用。制备的膜的热稳定性约为180℃。
Structural and Electrochemical Analysis of PMMA Based Gel Electrolyte Membranes
New gel polymer electrolytes containing poly(vinylidene chloride-co-acrylonitrile) and poly(methyl methacrylate) are prepared by solution casting method. With the addition of 60 wt.% of EC to PVdC-AN/PMMA blend, ionic conductivity value S cm−1 has been achieved. XRD and FT-IR studies have been conducted to investigate the structure and complexation in the polymer gel electrolytes. The FT-IR spectra show that the functional groups C=O and C≡N play major role in ion conduction. Thermal stability of the prepared membranes is found to be about 180°C.
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