木质生物质气化下吸填料床反应器中焦油的生成与分解

IF 1.2 4区 工程技术 Q3 THERMODYNAMICS Journal of Thermal Science and Technology Pub Date : 2021-01-01 DOI:10.1299/jtst.2021jtst0034
Ryo Yoshiie, A. Yamada, Yoko Nunome, Yasuaki Ueki, I. Naruse
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引用次数: 1

摘要

当生物质气化炉与燃气发动机系统直接连接时,应从合成气中除去焦油,以防止发动机发生故障。向下气流填充床气化炉具有低焦油排放的优点,因为合成气通过反应器下游的炭气化区,在那里焦油化合物可以被捕获和分解。然后,本研究的目的是确定下气流填充床反应器内的焦油分解行为。采用自热下吸填料床气化炉对木质生物质进行了气化实验。反应器高度为1000mm,内径为100mm。黑松木托盘连续地从顶部进入反应器。气化剂为空气,以0.49的空燃当量比引入反应器。填料层高度保持在600mm不变。反应器沿流动方向的壁面有11个热电偶和11个采样口。它们被用来测量反应堆的温度分布和气体成分。微气相色谱法测定n2、o2、CO、co2和h2, FIDGC法测定其他烃类。其中部分港口还对合成气中的焦油进行了冰浴二氯甲烷洗涤取样,并用TOF-MS分析了焦油化合物的分子量分布。结果证实,焦油和较大的碳氢化合物在上游生成,然后在下行反应器内下游分解。
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Tar generation and decomposition in downdraft packed bed reactor for woody biomass gasification
When the biomass gasifier is connected with a gas engine system directly, tar should be removed from the syngas to prevent the engine from breaking down. A downdraft packed bed gasifier has the advantage for low tar emission because the syngas passes through the char gasification zone downstream of the reactor, where tar compounds can be trapped and decomposed. Then, objective of this study is to confirm the tar decomposition behaviors inside the downdraft packed bed reactor. Woody biomass gasification experiments were carried out, using an auto-thermal downdraft packed bed gasifier. The reactor’s height and inner diameter were 1000mm and 100mm, respectively. Black pine pallets were continuously fed into the reactor from the top. The gasifying agent was air, which was introduced into the reactor at the air-fuel equivalent ratio of 0.49. The packed bed height was kept to be constant at 600mm. The reactor has eleven thermo-couples and eleven sampling ports at the wall along the flow direction. They were used for measurements of temperature profiles and gas compositions in the reactor. Micro-GC was used for the measurement of N 2 , O 2 , CO, CO 2 and H 2 , and FIDGC was used for other hydrocarbons. In some ports among them, tar in syngas was also sampled via dichloromethane scrubbing in ice-bath, and analyzed for molecular weight distributions of tar compounds by TOF-MS. As a result, tar and larger hydrocarbons were confirmed to be generated in the upstream, and then decomposed downstream inside the downdraft reactor.
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来源期刊
CiteScore
2.30
自引率
8.30%
发文量
0
审稿时长
5 months
期刊介绍: JTST covers a variety of fields in thermal engineering including heat and mass transfer, thermodynamics, combustion, bio-heat transfer, micro- and macro-scale transport phenomena and practical thermal problems in industrial applications.
期刊最新文献
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