{"title":"环氧沥青固化工艺研究","authors":"Jianming Wei, Yuzhen Zhang","doi":"10.1520/JTE20120136","DOIUrl":null,"url":null,"abstract":"In the present study, the curing process of epoxy asphalt was studied using Fourier transform infrared spectroscopy (FTIR) with attenuated total reflectance, fluorescent microscopy morphology, and surface free energy. FTIR was utilized to track the functional group changes in epoxy resin (part A) and asphalt containing a curing agent (part B) at different curing times. It is proposed that the curing agent (hardener) in the asphalt (part B) is a carboxylic acid. The curing process is the reaction between the carboxyl group and the epoxy group through which the ester carbonyl group is formed, whereby carbonyl acid molecules and epoxy molecules are bound together to form a cross-linked network. The fluorescent microscopy morphology analysis indicates that the cross-linked network did not form at the beginning of the reaction. In the cured epoxy asphalt system, the epoxy resin is the continuous phase, and the asphalt constitutes the dispersed phase. The sessile drop method was employed to measure the static contact angle between asphalt binders and three probe liquids. The surface free energies of the epoxy asphalt at different curing times were determined using the Owens–Wendt method. Contact angle and surface free energy measurements indicate that the polarity of epoxy asphalt was reduced and the dispersion part was increased with the extended curing time.","PeriodicalId":17109,"journal":{"name":"Journal of Testing and Evaluation","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2012-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"35","resultStr":"{\"title\":\"Study on the Curing Process of Epoxy Asphalt\",\"authors\":\"Jianming Wei, Yuzhen Zhang\",\"doi\":\"10.1520/JTE20120136\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In the present study, the curing process of epoxy asphalt was studied using Fourier transform infrared spectroscopy (FTIR) with attenuated total reflectance, fluorescent microscopy morphology, and surface free energy. FTIR was utilized to track the functional group changes in epoxy resin (part A) and asphalt containing a curing agent (part B) at different curing times. It is proposed that the curing agent (hardener) in the asphalt (part B) is a carboxylic acid. The curing process is the reaction between the carboxyl group and the epoxy group through which the ester carbonyl group is formed, whereby carbonyl acid molecules and epoxy molecules are bound together to form a cross-linked network. The fluorescent microscopy morphology analysis indicates that the cross-linked network did not form at the beginning of the reaction. In the cured epoxy asphalt system, the epoxy resin is the continuous phase, and the asphalt constitutes the dispersed phase. The sessile drop method was employed to measure the static contact angle between asphalt binders and three probe liquids. The surface free energies of the epoxy asphalt at different curing times were determined using the Owens–Wendt method. Contact angle and surface free energy measurements indicate that the polarity of epoxy asphalt was reduced and the dispersion part was increased with the extended curing time.\",\"PeriodicalId\":17109,\"journal\":{\"name\":\"Journal of Testing and Evaluation\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2012-12-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"35\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Testing and Evaluation\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1520/JTE20120136\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, CHARACTERIZATION & TESTING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Testing and Evaluation","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1520/JTE20120136","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, CHARACTERIZATION & TESTING","Score":null,"Total":0}
In the present study, the curing process of epoxy asphalt was studied using Fourier transform infrared spectroscopy (FTIR) with attenuated total reflectance, fluorescent microscopy morphology, and surface free energy. FTIR was utilized to track the functional group changes in epoxy resin (part A) and asphalt containing a curing agent (part B) at different curing times. It is proposed that the curing agent (hardener) in the asphalt (part B) is a carboxylic acid. The curing process is the reaction between the carboxyl group and the epoxy group through which the ester carbonyl group is formed, whereby carbonyl acid molecules and epoxy molecules are bound together to form a cross-linked network. The fluorescent microscopy morphology analysis indicates that the cross-linked network did not form at the beginning of the reaction. In the cured epoxy asphalt system, the epoxy resin is the continuous phase, and the asphalt constitutes the dispersed phase. The sessile drop method was employed to measure the static contact angle between asphalt binders and three probe liquids. The surface free energies of the epoxy asphalt at different curing times were determined using the Owens–Wendt method. Contact angle and surface free energy measurements indicate that the polarity of epoxy asphalt was reduced and the dispersion part was increased with the extended curing time.
期刊介绍:
This journal is published in six issues per year. Some issues, in whole or in part, may be Special Issues focused on a topic of interest to our readers.
This flagship ASTM journal is a multi-disciplinary forum for the applied sciences and engineering. Published bimonthly, the Journal of Testing and Evaluation presents new technical information, derived from field and laboratory testing, on the performance, quantitative characterization, and evaluation of materials. Papers present new methods and data along with critical evaluations; report users'' experience with test methods and results of interlaboratory testing and analysis; and stimulate new ideas in the fields of testing and evaluation.
Major topic areas are fatigue and fracture, mechanical testing, and fire testing. Also publishes review articles, technical notes, research briefs and commentary.