地球大气中的臭氧和紫外线

V. Gordienko, L. Gordienko, Ya.A. Honcharova
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摘要

本文考虑了地球大气中臭氧层的出现以及到达地表的太阳辐射中紫外线部分衰减的相关过程。研究表明,OL在保护生物体免受暴露于日照光谱短波长的破坏性影响方面的作用被极大地夸大了。臭氧是由电离层以下的紫外线辐射在空气中的氧分子分裂时产生的。当被紫外线吸收时,它就被破坏了。臭氧在大气的最低温度下存在的时间最长。这种情况和密度的增加导致了臭氧在对流层顶上方的积累,也就是臭氧形成的地方。同时存在的气体的数量是非常微不足道的——大约10⁻26空气。正是在这种情况下,才有可能估计它对紫外线吸收的贡献微乎其微。与它相比,空气分子对射线的散射要有效得多,尽管对紫外线中间部分的每一次吸收比一次散射的效果要大好几倍。人们可以同意通过与氟利昂和其他含卤素的气体(包括火山产生的卤素)反应来消除臭氧分子的想法。也有可能它与氢相互作用,但氢气是在大气中产生的,而不是在地球的内部。但是,改变臭氧层的过程,包括“臭氧空洞”的周期性形成,并不构成任何危险,而且是由自然现象而不是人类活动来解释的。为了挽救这一层而付出昂贵的代价是毫无意义的。另一方面,地面臭氧浓度恰恰在工业排放的影响下随时间增加。在发达国家的城市中,这种有毒气体的含量已经经常超过允许的水平,现在是采取更有效的措施来遏制其积累的时候了。
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Ozone and ultraviolet in the Earth's atmosphere
The appearance of the ozone layer (OL) in the Earth’s atmosphere and the associated processes of attenuation of the ultraviolet (UV) part of solar radiation reaching the surface are considered. It is shown that the role of OL in protecting living organisms from the destructive effects of exposure to the short-wavelength part of the insolation spectrum is immensely exaggerated. Ozone is generated by UV radiation below the ionosphere when oxygen molecules in the air are divided. When absorbed by UV rays, it is destroyed. Ozone exists for the longest time at minimum temperatures of the atmosphere. This circumstance and the increased density lead to the accumulation of O3 above the tropopause, where the OL is formed. The amount of simultaneously existing gas is extremely insignificant — about 10⁻⁶ air. It is this circumstance that makes it possible to estimate its contribution to the absorption of UV rays as vanishingly small. Compared with it, the scattering of rays by air molecules is incomparably more effective, although each single act of absorption of the middle part of the ultraviolet is several times greater than a single result of scattering. One can agree with the idea of the elimination of ozone molecules by reaction with freons and other gases containing halogens, including those of volcanic origin. It is also possible that it interacts with hydrogen, but H2 rather arising in the atmosphere, and not in the bowels of the Earth. But the processes of changing the OL, including the periodic formation of «ozone holes», do not pose any danger and are explained by natural phenomena, and not by human activity. A very expensive campaign to save the layer makes no sense. On the other hand, ground5level ozone concentration increases over time precisely under the influence of industrial emissions. In the cities of developed countries, the content of this poisonous gas already often exceeds permissible levels and it is time to take up more effective counteraction to its accumulation.
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