{"title":"化学运输固体固体，25[1]。s2 /莫斯2,TiSe 2/摩西2,ta 2/摩斯2和TaSe 2/摩西2","authors":"U. Hotje, R. Wartchow, M. Binnewies","doi":"10.15488/2385","DOIUrl":null,"url":null,"abstract":"In the systems TiS 2 /NbS 2 , TiSe 2 /NbSe 2 , NbS 2 /TaS 2 und NbSe 2 /TaSe 2 complete miscibility in the solid state has been observed by powder X-ray investigations. Mixed crystals as well as the binary compounds can be prepared by chemical vapour transport reactions using iodine as transport agent in the temperature gradient 1000 → 900 °C. The gaseous species TiI 3 (g), TiI 4 (g), NbI 4 (g) and TaI 4 (g) are responsible for the transport effect.","PeriodicalId":51215,"journal":{"name":"Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences","volume":"74 1","pages":"1235-1240"},"PeriodicalIF":0.8000,"publicationDate":"2005-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Chemischer Transport fester Lösungen, 25 [1]. Untersuchungen zur Mischphasenbildung und zum chemischen Transport in den Systemen TiS 2/MoS 2, TiSe 2/MoSe 2, TaS 2/MoS 2 und TaSe 2/MoSe 2\",\"authors\":\"U. Hotje, R. Wartchow, M. Binnewies\",\"doi\":\"10.15488/2385\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In the systems TiS 2 /NbS 2 , TiSe 2 /NbSe 2 , NbS 2 /TaS 2 und NbSe 2 /TaSe 2 complete miscibility in the solid state has been observed by powder X-ray investigations. Mixed crystals as well as the binary compounds can be prepared by chemical vapour transport reactions using iodine as transport agent in the temperature gradient 1000 → 900 °C. The gaseous species TiI 3 (g), TiI 4 (g), NbI 4 (g) and TaI 4 (g) are responsible for the transport effect.\",\"PeriodicalId\":51215,\"journal\":{\"name\":\"Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences\",\"volume\":\"74 1\",\"pages\":\"1235-1240\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2005-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.15488/2385\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.15488/2385","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Chemischer Transport fester Lösungen, 25 [1]. Untersuchungen zur Mischphasenbildung und zum chemischen Transport in den Systemen TiS 2/MoS 2, TiSe 2/MoSe 2, TaS 2/MoS 2 und TaSe 2/MoSe 2
In the systems TiS 2 /NbS 2 , TiSe 2 /NbSe 2 , NbS 2 /TaS 2 und NbSe 2 /TaSe 2 complete miscibility in the solid state has been observed by powder X-ray investigations. Mixed crystals as well as the binary compounds can be prepared by chemical vapour transport reactions using iodine as transport agent in the temperature gradient 1000 → 900 °C. The gaseous species TiI 3 (g), TiI 4 (g), NbI 4 (g) and TaI 4 (g) are responsible for the transport effect.
期刊介绍：
Zeitschrift fuer Naturforschung B (ZNB) publishes novel research in all areas of inorganic chemistry, organic chemistry, and analytical chemistry. In particular, the journal focuses on solid state chemistry, coordination chemistry, main group element chemistry, synthetic organic chemistry, natural product chemistry and, to a lesser extent, on analytical chemistry. For more than 65 years Zeitschrift fuer Naturforschung B has been open to contributions from all fields of experimental and theoretical chemistry. Zeitschrift fuer Naturforschung B publishes 12 issues per volume/year. Sometimes double issues occur.
Topics
Solid state chemistry
Coordination chemistry
Main group element chemistry
Organic chemistry
Natural product chemistry.
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