盐酸合成富锌铁矾的简易快速工艺

Q3 Materials Science Cerâmica Pub Date : 2022-09-01 DOI:10.1590/0366-69132022683873262
T. Carvalho, Michel B. B, M. G. Silva-Valenzuela, E. Hildebrando, R. Neves, F. Valenzuela-Díaz
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引用次数: 0

摘要

在过去的几十年里,粘土被用于健康和化妆品等领域。这就要求产品的纯度和均质性越来越高,这在天然粘土中是很难找到的。使用合成粘土是一种解决方案。为此,有必要探索其生产技术。本研究的重点是在低温、低压条件下简单、快速、经济地合成蒙脱石粘土,即静态法和动态法。为了调节反应的pH值,使其更接近理想的合成条件,使用了两种不同的酸:硝酸(文献中使用最广泛)和盐酸(更容易获得,也更便宜)。结果表明,该材料具有均匀的晶体特征,具有与蒙脱石相似的多孔结构。扫描电镜观察到约100 nm的小颗粒。采用两种不同的酸,两种合成方法都得到了史蒂文site粘土;盐酸静态法比较突出。其开发的更大实用性为大规模工业生产提供了更可行的选择。
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Simple and fast process using hydrochloric acid for producing synthetic zinc-rich stevensite
In the last decades, clays have been used in sectors such as health and cosmetics. This requires products that are increasingly pure and present homogeneous properties, hardly found in natural clays. The use of synthetic clays can be a solution. For this, it is necessary to explore techniques for their production. The main focus of this study was to synthesize a smectite clay in a simple, fast and economic way at low temperature and pressure, called static and dynamic methods. To regulate the pH of the reaction and bring it closer to the ideal synthesis conditions, two different acids were used: nitric acid (the most widely used in the literature) and hydrochloric acid (more accessible and cheaper). The results showed characteristics of uniform crystalline material with a porous structure similar to that of the smectite group. Small particle sizes of approximately 100 nm were observed by scanning electron microscopy. Stevensite clay was obtained by both synthesis methods using two different acids; the static method with hydrochloric acid stood out. The greater practicality in its development provides a more viable option for large-scale industrial production.
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来源期刊
Cerâmica
Cerâmica Materials Science-Ceramics and Composites
CiteScore
1.90
自引率
0.00%
发文量
37
审稿时长
10 weeks
期刊介绍: A Revista Cerâmica, órgão oficial da Associação Brasileira de Cerâmica (ABCERAM) publica contribuições originais de interesse na área de cerâmica, compreendendo arte cerâmica, abrasivos, biocerâmicas, cerâmicas avançadas, cerâmica branca, cerâmica de mesa, cerâmica eletroeletrônica, cerâmica estrutural, cerâmica magnética, cerâmica nuclear, cerâmica óptica, cerâmica química, cerâmica termomecânica, cerâmica vermelha, cimento, compósitos de matriz cerâmica, materiais refratários, materiais de revestimento, matérias-primas, vidrados, vidros e vitrocerâmicas, análise microestrutural, ciência básica, instrumentação, processos de fabricação, síntese de pós, técnicas de caracterização etc.
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