Wolframhexachlorid的反应应将2,2-Dimethylpropylidinphosphan: Kristallstrukturen WCl5P2 (C5H9) 3、WCl4P5 (C5H9) 5 [C3 (C4H9) 3] + [WCl5 (C4H9C≡CC4H9]——

IF 0.8 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences Pub Date : 1991-01-01 DOI:10.18419/OPUS-7391

F. Weller, I. Pauls, K. Dehnicke, G. Becker

{"title":"Wolframhexachlorid的反应应将2,2-Dimethylpropylidinphosphan: Kristallstrukturen WCl5P2 (C5H9) 3、WCl4P5 (C5H9) 5 [C3 (C4H9) 3] + [WCl5 (C4H9C≡CC4H9]——","authors":"F. Weller, I. Pauls, K. Dehnicke, G. Becker","doi":"10.18419/OPUS-7391","DOIUrl":null,"url":null,"abstract":"The reaction of tungsten hexachloride with excess 2,2-dimethylpropylidynephosphane, C 4 H 9 -C≡P, leads to the tungsten phosphaalkyne clusters WCl 5 P 2 (C 5 H 9 ) 3 and WCl 4 P 5 (C 5 H 9 ) 5 , as well as to the tris(t-butyl)cyclopropenium pentachloro tungsten alkyne complex [C 3 (C 4 H 9 ) 3 ] + [WCl 5 (C 4 H 9 C≡CC 4 H 9 )] − . All complexes were characterized by X-ray structure determinations","PeriodicalId":51215,"journal":{"name":"Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences","volume":"46 1","pages":"519-529"},"PeriodicalIF":0.8000,"publicationDate":"1991-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Die Reaktionen von Wolframhexachlorid mit überschüssigem 2,2-Dimethylpropylidinphosphan : die Kristallstrukturen von WCl5P2(C5H9)3, WCl4P5(C5H9)5 und [C3(C4H9)3]+[WCl5(C4H9C≡CC4H9]-\",\"authors\":\"F. Weller, I. Pauls, K. Dehnicke, G. Becker\",\"doi\":\"10.18419/OPUS-7391\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The reaction of tungsten hexachloride with excess 2,2-dimethylpropylidynephosphane, C 4 H 9 -C≡P, leads to the tungsten phosphaalkyne clusters WCl 5 P 2 (C 5 H 9 ) 3 and WCl 4 P 5 (C 5 H 9 ) 5 , as well as to the tris(t-butyl)cyclopropenium pentachloro tungsten alkyne complex [C 3 (C 4 H 9 ) 3 ] + [WCl 5 (C 4 H 9 C≡CC 4 H 9 )] − . All complexes were characterized by X-ray structure determinations\",\"PeriodicalId\":51215,\"journal\":{\"name\":\"Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences\",\"volume\":\"46 1\",\"pages\":\"519-529\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"1991-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.18419/OPUS-7391\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.18419/OPUS-7391","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

六氯化钨的反应2,过剩2-dimethylpropylidynephosphane, 4 H 9 C - C≡P,导致钨phosphaalkyne集群水控制法5 P 2 (C 5 H 9) 3和水控制法4 P (C 5 H 9) 5,以及三羟甲基氨基甲烷(叔丁基)cyclopropenium五氯液钨炔复杂[C 3 (C 4 H 9) 3] +[水控制法5 (4 H 9 C≡CC 4 H 9)]−。所有配合物均通过x射线结构测定进行了表征

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Die Reaktionen von Wolframhexachlorid mit überschüssigem 2,2-Dimethylpropylidinphosphan : die Kristallstrukturen von WCl5P2(C5H9)3, WCl4P5(C5H9)5 und [C3(C4H9)3]+[WCl5(C4H9C≡CC4H9]-

The reaction of tungsten hexachloride with excess 2,2-dimethylpropylidynephosphane, C 4 H 9 -C≡P, leads to the tungsten phosphaalkyne clusters WCl 5 P 2 (C 5 H 9 ) 3 and WCl 4 P 5 (C 5 H 9 ) 5 , as well as to the tris(t-butyl)cyclopropenium pentachloro tungsten alkyne complex [C 3 (C 4 H 9 ) 3 ] + [WCl 5 (C 4 H 9 C≡CC 4 H 9 )] − . All complexes were characterized by X-ray structure determinations

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences 化学-无机化学与核化学

CiteScore

1.80

自引率

12.50%

发文量

期刊介绍： Zeitschrift fuer Naturforschung B (ZNB) publishes novel research in all areas of inorganic chemistry, organic chemistry, and analytical chemistry. In particular, the journal focuses on solid state chemistry, coordination chemistry, main group element chemistry, synthetic organic chemistry, natural product chemistry and, to a lesser extent, on analytical chemistry. For more than 65 years Zeitschrift fuer Naturforschung B has been open to contributions from all fields of experimental and theoretical chemistry. Zeitschrift fuer Naturforschung B publishes 12 issues per volume/year. Sometimes double issues occur. Topics Solid state chemistry Coordination chemistry Main group element chemistry Organic chemistry Natural product chemistry.