氧化铝纤维和原位莫来石晶须增强大尺寸建筑陶瓷薄板的力学性能

IF 0.9 4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Processing and Application of Ceramics Pub Date : 2022-01-01 DOI:10.2298/pac2202183z
Xinzi Zhong, Liyun Cao, Jianfeng Huang, Yijun Liu, Haibo Ouyang, Qinggang Wang
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引用次数: 3

摘要

采用可控纤维分散工艺,采用快烧结法制备了900 ~ 1800 ~ 2.5mm的纤维增强建筑陶瓷薄板,具有优异的力学性能。研究了球磨时间对氧化铝纤维分散性、平均长径比和微观结构的影响。同时,研究了氧化铝纤维含量对薄陶瓷板的容重、吸水率、相变和微观结构的影响。研究发现,两步球磨工艺可以有效控制氧化铝纤维的平均长径比,实现纤维与陶瓷粉的良好分散混合。陶瓷的容重和抗弯强度随纤维含量从0 ~ 5wt.%增加而增大,随纤维含量从5 ~ 15wt.%增加而减小。快速烧结原位形成的莫来石晶须有利于保护纤维和纤维/基体界面。当纤维含量为5wt .%时,弯曲强度和断裂韧性达到最大值147MPa,纤维含量为2.6MPa?当纤维含量为9 wt.%时为M1/2,对应于快速烧结过程中氧化铝纤维的强化和纤维/基体界面和基体中莫来石晶须的形成。
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Mechanical properties of large-sized thin architectural ceramic plate enhanced by alumina fibres and in situ mullite whiskers
The fibres reinforced thin architectural ceramic plates of 900?1800?2.5mm with excellent mechanical properties were prepared by fast-sintering method using a controllable fibre dispersion process. The effects of ball-milling time on dispersity, average length-to-diameter ratio and microstructure of alumina fibres were investigated. Meanwhile, the effects of alumina fibre contents on the bulk density, water absorption, phase transformation and microstructure of the thin ceramic plate were researched. It was found that the two-step ball-milling process can effectively control the average length-to-diameter ratio of alumina fibres, achieving a good dispersion mixture of fibres and ceramic powders. Ceramics bulk density and bending strength increase with fibre contents rise from 0 to 5 wt.% and then decrease with further fibre content addition from 5 to 15wt.%. The in situ formed mullite whiskers via fast-sintering method are beneficial for protecting fibres and fibre/matrix interfaces. The maximum value of bending strength and fracture toughness reach 147MPa for 5 wt.% fibre contents and 2.6MPa?m1/2 for 9 wt.%fibre contents, corresponding to the strengthening of alumina fibres and the formation of mullite whiskers in fibre/matrix interfaces and matrix via fast-sintering process.
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来源期刊
Processing and Application of Ceramics
Processing and Application of Ceramics MATERIALS SCIENCE, CERAMICS-
CiteScore
1.90
自引率
9.10%
发文量
14
审稿时长
10 weeks
期刊介绍: Information not localized
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