N. Labus, J. Krstić, Srdjan D. Matijašević, V. Pavlović
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Oxide powder mixture with poly-vinyl alcohol (PVA) and added polyethylene glycol (PEG) as plasticizer
Powder mixture consisted of ZnO, Mn2O3 (MnCO3) and Fe2O3 blended powders, was found laminating during compaction. Polyvinyl alcohol (PVA) and a combination of PVA with polyethylene glycol (PEG) added as a plasticizer, were introduced as polymer binders to improve the compaction of oxide mixtures. It has been done by forming a suspension of oxide mixture and varying the polymer solution concentration and composition. By evaporating the solvent, new materials were obtained, which consist of oxide particles bound via polymer. In such a manner obtained hybrid materials were characterized with attenuated total reflection Fourier transformed infrared (ATR-FTIR) spectroscopy, differential thermal analysis (DTA) and transmission electron microscopy (TEM). The oxide polymer material was compacted at 200 MPa and the expansion of this compact during heating was monitored in temperature range up to 550 ?C with dilatometer. It was found that PVA forms graft polymer with PEG and specific interaction with oxide particles surface was revealed.
期刊介绍：
Science of Sintering is a unique journal in the field of science and technology of sintering.
Science of Sintering publishes papers on all aspects of theoretical and experimental studies, which can contribute to the better understanding of the behavior of powders and similar materials during consolidation processes. Emphasis is laid on those aspects of the science of materials that are concerned with the thermodynamics, kinetics and mechanism of sintering and related processes. In accordance with the significance of disperse materials for the sintering technology, papers dealing with the question of ultradisperse powders, tribochemical activation and catalysis are also published.
Science of Sintering journal is published four times a year.
Types of contribution: Original research papers, Review articles, Letters to Editor, Book reviews.
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