熔盐对加铁CuNiSi合金力学性能和显微组织的影响

IF 1.4 4区 材料科学 Q3 MATERIALS SCIENCE, CERAMICS Science of Sintering Pub Date : 2023-01-01 DOI:10.2298/sos230327028a
M. Akkaş
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引用次数: 0

摘要

本研究采用熔盐(KBr)粉末冶金法制备了CuNiSi合金。在Cu、Ni和Si粉末混合物中,分别以2.5%、5%和7.5%的速度加入Fe,在400 rpm下机械合金化4小时。将制备好的粉末混合物在600 MPa的压力下冷压,900℃下烧结3小时。在氩气环境中。详细分析了制备样品的相形成、显微组织、显微硬度、电导率和腐蚀性能。利用扫描电子显微镜(SEM)检测制备样品的微观结构变化,用x射线衍射仪(XRD)测定材料内部结构中形成的相。采用显微硬度测量仪对试样进行了硬度分析,以确定试样的力学性能。制备的CuNiSi和CuNiSiFe合金的电导率由于铁比的增加而被测定。制备的样品在3.5% NaCl溶液中采用动电位极化曲线进行腐蚀试验。在熔融盐(KBr)中成功制备了铁增强CuNiSi复合材料。CuNiSi合金的显微组织以典型的大颗粒和小颗粒为主。Fe元素在CuNiSi合金中均匀分散,而不是被Ni元素分离。铁颗粒降低了所生产合金的硬度。随着铁添加量的增加,电导率随电压的增加而变化,结果表明,含铁量为7.5%的样品电导率最高。结果表明,随着Fe用量的增加,合金的力学性能和耐蚀性均有所提高。
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The effect of molten salt on the mechanical properties and microstructure of CuNiSi alloys with reinforced Fe
In this study, CuNiSi alloys were produced using powder metallurgy in molten salt (KBr). In the Cu, Ni, and Si powder mixture, Fe was added at a rate of 2.5%, 5 and 7.5% and mechanical alloying was carried out for 4 hours at 400 rpm. Prepared powder mixtures were cold pressed under 600 MPa pressure and sintered for 3 hours at 900 ? in an argon atmosphere. Phase formation, microstructure, microhardness, electrical conductivity, and corrosion of the produced samples were analyzed in detail. Scanning electron microscope (SEM) was used to detect the changes in the microstructure of the produced samples, and an X-ray diffractogram (XRD) was used to determine the phases formed in the internal structure of the materials. In order to determine the mechanical properties of the produced samples, hardness analyzes were made with a microhardness measuring device. The electrical conductivity properties of the produced CuNiSi and CuNiSiFe alloys were determined due to the increase in the Fe ratio. Corrosion tests of the produced samples were determined by potentiodynamic polarization curves in a 3.5% NaCl solution. Fe-reinforced CuNiSi composite materials have been successfully produced in molten salt (KBr). CuNiSi alloy, the microstructure is dominated by the typical large and small particles. Fe element is homogeneously dispersed in the CuNiSi alloy instead of being separated using the Ni element. Fe particles have decreased the hardness of produced alloys. The electrical conductivity properties changed with increasing voltages depending on the increase of Fe supplementation, and as a result, the sample containing 7.5% Fe had the best electrical conductivity values. Results showed that by increasing the amount of Fe, the mechanical properties and corrosion resistance increased.
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来源期刊
Science of Sintering
Science of Sintering 工程技术-材料科学:硅酸盐
CiteScore
2.50
自引率
46.70%
发文量
20
审稿时长
3.3 months
期刊介绍: Science of Sintering is a unique journal in the field of science and technology of sintering. Science of Sintering publishes papers on all aspects of theoretical and experimental studies, which can contribute to the better understanding of the behavior of powders and similar materials during consolidation processes. Emphasis is laid on those aspects of the science of materials that are concerned with the thermodynamics, kinetics and mechanism of sintering and related processes. In accordance with the significance of disperse materials for the sintering technology, papers dealing with the question of ultradisperse powders, tribochemical activation and catalysis are also published. Science of Sintering journal is published four times a year. Types of contribution: Original research papers, Review articles, Letters to Editor, Book reviews.
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