建立了一种测量熔融氧化物表面张力的新方法

IF 1.1 4区 工程技术 Q4 Engineering High Temperatures-high Pressures Pub Date : 2021-01-01 DOI:10.32908/hthp.v50.857
Toshiki Kondo, H. Muta, Y. Ohishi
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引用次数: 3

摘要

熔融氧化物的物理性质,如粘度和表面张力,在各个领域都很重要。然而,由于熔融氧化物的高熔点、高反应性和高蒸气压,测量其性质是非常困难的。因此,熔融氧化物的物理性质很少被报道。因此,我们开发了一种新方法,称为“撞击法”,用于在很短的时间内测量熔融氧化物的表面张力,使用空气动力学悬浮技术。在这项工作中,我们开发了一种测量熔融Al2O3表面张力的装置,并将其与其他方法的测量值进行了比较,作为参考值。结果表明:在2500 K左右,Al2O3熔液的表面张力约为0.72 N/m,接近参考值;此外,可以在很短的时间内(大约80毫秒)获得测量结果。因此,可以期望使用该方法测量ZrO2和UO2等高蒸汽压熔融材料的表面张力。
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Development of a new method to measure surface tension of molten oxides
Physical properties of molten oxides such as viscosity and surface tension are important in various fields. However, it is very difficult to measure the properties of molten oxides owing to their high melting points, high reactivity, and high vapor pressure. Hence, the physical properties of molten oxides are scarcely reported. Therefore, we developed a new method, termed the �impingement method,� for measuring the surface tension of molten oxides in a very short time, using the aerodynamic levitation technique. In this work, we developed an apparatus for measuring the surface tension of molten Al2O3 and compared the value with that of other methods, considered as reference values. Results showed that the surface tension of molten Al2O3 was approximately 0.72 N/m at around 2500 K, which is close to the reference value; moreover, the measurements could be obtained in a very short time (approximately 80 ms). Thus, it is expected that the surface tension of molten materials with high vapor pressures such as ZrO2 and UO2 can be measured using this method.
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来源期刊
High Temperatures-high Pressures
High Temperatures-high Pressures THERMODYNAMICS-MECHANICS
CiteScore
1.00
自引率
9.10%
发文量
6
期刊介绍: High Temperatures – High Pressures (HTHP) is an international journal publishing original peer-reviewed papers devoted to experimental and theoretical studies on thermophysical properties of matter, as well as experimental and modelling solutions for applications where control of thermophysical properties is critical, e.g. additive manufacturing. These studies deal with thermodynamic, thermal, and mechanical behaviour of materials, including transport and radiative properties. The journal provides a platform for disseminating knowledge of thermophysical properties, their measurement, their applications, equipment and techniques. HTHP covers the thermophysical properties of gases, liquids, and solids at all temperatures and under all physical conditions, with special emphasis on matter and applications under extreme conditions, e.g. high temperatures and high pressures. Additionally, HTHP publishes authoritative reviews of advances in thermophysics research, critical compilations of existing data, new technology, and industrial applications, plus book reviews.
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