{"title":"建立了一种测量熔融氧化物表面张力的新方法","authors":"Toshiki Kondo, H. Muta, Y. Ohishi","doi":"10.32908/hthp.v50.857","DOIUrl":null,"url":null,"abstract":"Physical properties of molten oxides such as viscosity and surface tension are important in various fields. However, it is very difficult to measure the properties of molten oxides owing to their high melting points, high reactivity, and high vapor pressure. Hence, the physical properties of molten oxides are scarcely reported. Therefore, we developed a new method, termed the �impingement method,� for measuring the surface tension of molten oxides in a very short time, using the aerodynamic levitation technique. In this work, we developed an apparatus for measuring the surface tension of molten Al2O3 and compared the value with that of other methods, considered as reference values. Results showed that the surface tension of molten Al2O3 was approximately 0.72 N/m at around 2500 K, which is close to the reference value; moreover, the measurements could be obtained in a very short time (approximately 80 ms). Thus, it is expected that the surface tension of molten materials with high vapor pressures such as ZrO2 and UO2 can be measured using this method.","PeriodicalId":12983,"journal":{"name":"High Temperatures-high Pressures","volume":"1 1","pages":""},"PeriodicalIF":1.1000,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Development of a new method to measure surface tension of molten oxides\",\"authors\":\"Toshiki Kondo, H. Muta, Y. Ohishi\",\"doi\":\"10.32908/hthp.v50.857\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Physical properties of molten oxides such as viscosity and surface tension are important in various fields. However, it is very difficult to measure the properties of molten oxides owing to their high melting points, high reactivity, and high vapor pressure. Hence, the physical properties of molten oxides are scarcely reported. Therefore, we developed a new method, termed the �impingement method,� for measuring the surface tension of molten oxides in a very short time, using the aerodynamic levitation technique. In this work, we developed an apparatus for measuring the surface tension of molten Al2O3 and compared the value with that of other methods, considered as reference values. Results showed that the surface tension of molten Al2O3 was approximately 0.72 N/m at around 2500 K, which is close to the reference value; moreover, the measurements could be obtained in a very short time (approximately 80 ms). Thus, it is expected that the surface tension of molten materials with high vapor pressures such as ZrO2 and UO2 can be measured using this method.\",\"PeriodicalId\":12983,\"journal\":{\"name\":\"High Temperatures-high Pressures\",\"volume\":\"1 1\",\"pages\":\"\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2021-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"High Temperatures-high Pressures\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.32908/hthp.v50.857\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"High Temperatures-high Pressures","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.32908/hthp.v50.857","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Engineering","Score":null,"Total":0}
Development of a new method to measure surface tension of molten oxides
Physical properties of molten oxides such as viscosity and surface tension are important in various fields. However, it is very difficult to measure the properties of molten oxides owing to their high melting points, high reactivity, and high vapor pressure. Hence, the physical properties of molten oxides are scarcely reported. Therefore, we developed a new method, termed the �impingement method,� for measuring the surface tension of molten oxides in a very short time, using the aerodynamic levitation technique. In this work, we developed an apparatus for measuring the surface tension of molten Al2O3 and compared the value with that of other methods, considered as reference values. Results showed that the surface tension of molten Al2O3 was approximately 0.72 N/m at around 2500 K, which is close to the reference value; moreover, the measurements could be obtained in a very short time (approximately 80 ms). Thus, it is expected that the surface tension of molten materials with high vapor pressures such as ZrO2 and UO2 can be measured using this method.
期刊介绍:
High Temperatures – High Pressures (HTHP) is an international journal publishing original peer-reviewed papers devoted to experimental and theoretical studies on thermophysical properties of matter, as well as experimental and modelling solutions for applications where control of thermophysical properties is critical, e.g. additive manufacturing. These studies deal with thermodynamic, thermal, and mechanical behaviour of materials, including transport and radiative properties. The journal provides a platform for disseminating knowledge of thermophysical properties, their measurement, their applications, equipment and techniques. HTHP covers the thermophysical properties of gases, liquids, and solids at all temperatures and under all physical conditions, with special emphasis on matter and applications under extreme conditions, e.g. high temperatures and high pressures. Additionally, HTHP publishes authoritative reviews of advances in thermophysics research, critical compilations of existing data, new technology, and industrial applications, plus book reviews.