基于微生物电解池的二氧化碳甲烷化工艺优化策略

4区 材料科学 Q2 Environmental Science Journal of Renewable Materials Pub Date : 2023-01-01 DOI:10.32604/jrm.2023.027749
Qifen Li, Xiaoxiao Yan, Yongwen Yang, Liting Zhang, Yuanbo Hou
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引用次数: 0

摘要

微生物电解电池(MEC)是一种以电能为能量输入,以微生物为催化剂生产燃料和化学品的电化学反应装置。再生式电化学系统是利用可再生能源提供电压环境,对生物固碳技术产生的甲烷气体进行MEC改进的系统。针对可再生电力波动扰动和系统启动时间长的影响,分析了调节电压参数变化和活性污泥预处理两种策略对可再生气体电化学系统产甲烷效率的特点。在该系统中,通过间歇增压启动策略,再生式电化学系统的产甲烷率提高了1.4倍;在间歇增压的基础上,采用污泥热解预处理启动策略,再生式电化学系统甲烷产率提高2倍,启动时间缩短至10天。同时,根据电源输入波动和间歇性的仿真试验结果,其系统运行的稳定性标准差为原系统运行的75%,恢复率提高约1倍。本研究可为基于可再生能源的微生物CO2甲烷化技术的早期工业应用提供理论依据和技术参考。
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Optimisation Strategy of Carbon Dioxide Methanation Technology Based on Microbial Electrolysis Cells
Microbial Electrolytic Cell (MEC) is an electrochemical reaction device that uses electrical energy as an energy input and microorganisms as catalysts to produce fuels and chemicals. The regenerative electrochemical system is a MEC improvement system for methane gas produced by biological carbon sequestration technology using renewable energy sources to provide a voltage environment. In response to the influence of fluctuating disturbances of renewable electricity and the long system start-up time, this paper analyzes the characteristics of two strategies, regulating voltage parameter changes and activated sludge pretreatment, on the methane production efficiency of the renewable gas electrochemical system. In this system, the methane production rate of regenerative electrochemical system is increased by 1.4 times through intermittent boosting start-up strategy; based on intermittent boosting, the methane production rate of regenerative electrochemical system is increased by 2 times through sludge pyrolysis pretreatment start-up strategy, and the start-up time is reduced to 10 days. Meanwhile, according to the simulation test results of power input fluctuation and intermittency, the stability standard deviation of its system operation is 75% of the original one, and the recovery rate is about 1 times higher. This study can provide a theoretical basis and technical reference for the early industrial application of microbial CO2 methanation technology based on renewable energy.
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来源期刊
Journal of Renewable Materials
Journal of Renewable Materials Materials Science, Composites; Polymer Science; Green & Sustainable Science & Technology-
CiteScore
4.10
自引率
0.00%
发文量
125
期刊介绍: This journal publishes high quality peer reviewed original research and review articles on macromolecules and additives obtained from renewable/biobased resources. Utilizing a multidisciplinary approach, JRM introduces cutting-edge research on biobased monomers, polymers, additives (both organic and inorganic), their blends and composites. JRM showcases both fundamental aspects and applications of renewable materials. The fundamental topics include the synthesis and polymerization of biobased monomers and macromonomers, the chemical modification of natural polymers, as well as the characterization, structure-property relationships, processing, recycling, bio and environmental degradation and life cycle analysis of the ensuing materials, in view of their potential applications. Within this sustainability approach, green chemistry processes and studies falling within biorefinery contexts are strongly favored.
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